Pressure dependence of intermolecular interactions in the genuine organic β-phase p-nitrophenyl nitronyl nitroxide crystal accompanying a ferro- to antiferromagnetic transition

Kazuyoshi Takeda, Masaki Mito, Tatsuya Kawae, Masaharu Takumi, Kiyofumi Nagata, Masafumi Tamura, Minoru Kinoshita

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

The ferromagnetic to antiferromagnetic transition in genuine organic ferromagnets has been observed for the first time in the pressurized β-phase p-nitrophenyl nitronyl nitroxide crystal at the pressure around pc = 6.5 ± 0.5 kbar below 0.5 K, through the measurements of magnetic susceptibility and magnetization. The pressure dependence of the lattice parameters of its F2dd crystal structure, examined up to 12.6 kbar at room temperature, shows an anomaly near pc. At ambient pressure, the effective intermolecular interaction is estimated to be z̃J̃/kB= 2.3 K by the analysis of the magnetic heat capacity in the external field of 10 and 30 kOe. The Curie temperature in the ferromagnetic state at p < pc decreases with increasing pressure. In the antiferromagnetic state at p > pc, however, the transition temperature starts to increase. The variation of intermolecular interactions under pressure, including their signs, is discussed on the basis of the charge-transfer mechanism and the recent ab initio method for the exchange interactions.

Original languageEnglish
Pages (from-to)671-676
Number of pages6
JournalJournal of Physical Chemistry B
Volume102
Issue number4
Publication statusPublished - Jan 22 1998

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pressure dependence
Pressure
Crystals
crystals
interactions
Temperature
Magnets
Transition Temperature
Curie temperature
lattice parameters
Exchange interactions
Magnetic susceptibility
transition temperature
charge transfer
specific heat
anomalies
Superconducting transition temperature
Lattice constants
Specific heat
magnetic permeability

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this

Pressure dependence of intermolecular interactions in the genuine organic β-phase p-nitrophenyl nitronyl nitroxide crystal accompanying a ferro- to antiferromagnetic transition. / Takeda, Kazuyoshi; Mito, Masaki; Kawae, Tatsuya; Takumi, Masaharu; Nagata, Kiyofumi; Tamura, Masafumi; Kinoshita, Minoru.

In: Journal of Physical Chemistry B, Vol. 102, No. 4, 22.01.1998, p. 671-676.

Research output: Contribution to journalArticle

Takeda, Kazuyoshi ; Mito, Masaki ; Kawae, Tatsuya ; Takumi, Masaharu ; Nagata, Kiyofumi ; Tamura, Masafumi ; Kinoshita, Minoru. / Pressure dependence of intermolecular interactions in the genuine organic β-phase p-nitrophenyl nitronyl nitroxide crystal accompanying a ferro- to antiferromagnetic transition. In: Journal of Physical Chemistry B. 1998 ; Vol. 102, No. 4. pp. 671-676.
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AU - Takumi, Masaharu

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AU - Tamura, Masafumi

AU - Kinoshita, Minoru

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