Programmed asymmetrical trimer formation of β-alkyl N-confused porphyrin zinc(II) complex

Motoki Toganoh, Hiroaki Ogawa, Tatsuki Morimoto, Hiroyuki Furuta

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Self-coordination of β-alkyl N-confused porphyrin (NCP) zinc(II) complexes has been studied to reveal that asymmetrical trimers formed exclusively. A key factor to control the configuration of the trimers (symmetric or asymmetric) has been studied theoretically, and revealed that the steric environment around the peripheral nitrogen atoms as well as rotational angles of the confused pyrrole rings play a crucial role in trimer formation of β-alkyl NCP zinc(II) complexes.

Original languageEnglish
Pages (from-to)324-330
Number of pages7
JournalSupramolecular Chemistry
Volume21
Issue number3-4
DOIs
Publication statusPublished - Nov 24 2009

Fingerprint

Pyrroles
Nitrogen
Atoms
zinc hematoporphyrin

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Programmed asymmetrical trimer formation of β-alkyl N-confused porphyrin zinc(II) complex. / Toganoh, Motoki; Ogawa, Hiroaki; Morimoto, Tatsuki; Furuta, Hiroyuki.

In: Supramolecular Chemistry, Vol. 21, No. 3-4, 24.11.2009, p. 324-330.

Research output: Contribution to journalArticle

@article{1e40b15101ce43ea9560c45cd801286d,
title = "Programmed asymmetrical trimer formation of β-alkyl N-confused porphyrin zinc(II) complex",
abstract = "Self-coordination of β-alkyl N-confused porphyrin (NCP) zinc(II) complexes has been studied to reveal that asymmetrical trimers formed exclusively. A key factor to control the configuration of the trimers (symmetric or asymmetric) has been studied theoretically, and revealed that the steric environment around the peripheral nitrogen atoms as well as rotational angles of the confused pyrrole rings play a crucial role in trimer formation of β-alkyl NCP zinc(II) complexes.",
author = "Motoki Toganoh and Hiroaki Ogawa and Tatsuki Morimoto and Hiroyuki Furuta",
year = "2009",
month = "11",
day = "24",
doi = "10.1080/10610270802588293",
language = "English",
volume = "21",
pages = "324--330",
journal = "Supramolecular Chemistry",
issn = "1061-0278",
publisher = "Taylor and Francis Ltd.",
number = "3-4",

}

TY - JOUR

T1 - Programmed asymmetrical trimer formation of β-alkyl N-confused porphyrin zinc(II) complex

AU - Toganoh, Motoki

AU - Ogawa, Hiroaki

AU - Morimoto, Tatsuki

AU - Furuta, Hiroyuki

PY - 2009/11/24

Y1 - 2009/11/24

N2 - Self-coordination of β-alkyl N-confused porphyrin (NCP) zinc(II) complexes has been studied to reveal that asymmetrical trimers formed exclusively. A key factor to control the configuration of the trimers (symmetric or asymmetric) has been studied theoretically, and revealed that the steric environment around the peripheral nitrogen atoms as well as rotational angles of the confused pyrrole rings play a crucial role in trimer formation of β-alkyl NCP zinc(II) complexes.

AB - Self-coordination of β-alkyl N-confused porphyrin (NCP) zinc(II) complexes has been studied to reveal that asymmetrical trimers formed exclusively. A key factor to control the configuration of the trimers (symmetric or asymmetric) has been studied theoretically, and revealed that the steric environment around the peripheral nitrogen atoms as well as rotational angles of the confused pyrrole rings play a crucial role in trimer formation of β-alkyl NCP zinc(II) complexes.

UR - http://www.scopus.com/inward/record.url?scp=70449725127&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=70449725127&partnerID=8YFLogxK

U2 - 10.1080/10610270802588293

DO - 10.1080/10610270802588293

M3 - Article

AN - SCOPUS:70449725127

VL - 21

SP - 324

EP - 330

JO - Supramolecular Chemistry

JF - Supramolecular Chemistry

SN - 1061-0278

IS - 3-4

ER -