Promoting aqueous and transport characteristics of highly reactive nanoscale zero valent iron via different layered hydroxide coatings

Ibrahim Maamoun, Osama Eljamal, Ramadan Eljamal, Omar Falyouna, Yuji Sugihara

Research output: Contribution to journalArticle

Abstract

In this study, nanoscale zero valent iron (Fe0) was coated with different layered hydroxide coatings (Mg/Al/Ca(OH)N) to enhance its suspension stability in aqueous solution and transportability within the porous media. Morphological characteristics, crystallinity and surface elemental composition of the synthesized bare (Fe0) and coated (C-Fe0) were investigated using TEM, XRD and SEM-EDS analyses respectively. Suspension stability of Fe0 and C-Fe0 suspensions with different [Mg or Al or Ca/Fe: 0.2–1.0 wt/wt] coating ratios was investigated through several sets of 180 min settlement experiments. Moreover, packed-column experiments were conducted to evaluate the mobility of the prepared materials through porous media. Settlement results were highly consistent with mobility investigation, where C-Fe0 [Mg/Fe]1.0 showed the best performance in both with around 88% relative suspension efficiency and 93% penetration efficiency (5 times higher than Fe0). A reciprocal relation was found between particle size, crystallinity and reactivity of the C-Fe0, where the finest sizes exhibited higher crystallinity and better removal of the two targeted nutrients. Furthermore, the progressive dissolution of the Mg(OH)2 shell compared with the other coating materials resulted in its superior prolonged reactivity. The presented C-Fe0 could be promising towards enhanced performance of the reactive nanoparticles in the real water treatment applications.

Original languageEnglish
Article number145018
JournalApplied Surface Science
Volume506
DOIs
Publication statusPublished - Mar 15 2020

Fingerprint

hydroxides
Suspensions
Iron
coatings
iron
crystallinity
Coatings
Porous materials
reactivity
Water treatment
Nutrients
water treatment
Energy dispersive spectroscopy
nutrients
Dissolution
porous materials
Experiments
Particle size
Nanoparticles
Transmission electron microscopy

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Condensed Matter Physics
  • Physics and Astronomy(all)
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films

Cite this

Promoting aqueous and transport characteristics of highly reactive nanoscale zero valent iron via different layered hydroxide coatings. / Maamoun, Ibrahim; Eljamal, Osama; Eljamal, Ramadan; Falyouna, Omar; Sugihara, Yuji.

In: Applied Surface Science, Vol. 506, 145018, 15.03.2020.

Research output: Contribution to journalArticle

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AU - Sugihara, Yuji

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