Protection and deprotection approach for the introduction of functional groups into metal-organic frameworks

Teppei Yamada, Hiroshi Kitagawa

Research output: Contribution to journalArticle

106 Citations (Scopus)

Abstract

A noncoordinating hydroxyl group was introduced into a metal-organic framework (MOF) by a procedure involving a protection, complexation, and deprotection (PCD) reaction sequence, and the crystal structure of a novel MOF, [Zn(dhybdc)(bpy)]64DMF (1), was determined. 1 did not have an interpenetrated structure. The three-dimensional pores had arge apertures. Results showed that the PCD method is a novel synthetic method for the introduction of various functional groups into MOFs.

Original languageEnglish
Pages (from-to)6312-6313
Number of pages2
JournalJournal of the American Chemical Society
Volume131
Issue number18
DOIs
Publication statusPublished - May 13 2009

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

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