Proton-coupled electron shuttling in a covalently linked ruthenium-copper heterodinuclear complex

Tomoya Ishizuka, Kengo Tobita, Yuichi Yano, Yoshihito Shiota, Kazunari Yoshizawa, Shunichi Fukuzumi, Takahiko Kojima

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

A heterodinuclear complex based on a RuII-TPA [TPA = tris(2-pyridylmethyl)amine] complex having a peripheral CuII (bpy)2 (bpy = 2,2'-bipyridine) group bonded through an amide linkage displayed reversible intramolecular electron transfer between the Ru and Cu complex units that can be controlled by protonation and deprotonation of the bridging amide moiety.

Original languageEnglish
Pages (from-to)18570-18573
Number of pages4
JournalJournal of the American Chemical Society
Volume133
Issue number46
DOIs
Publication statusPublished - Nov 23 2011

Fingerprint

Ruthenium
Amides
Protons
Copper
Electrons
2,2'-Dipyridyl
Deprotonation
Protonation
Amines
tris(2-pyridylmethyl)amine

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Proton-coupled electron shuttling in a covalently linked ruthenium-copper heterodinuclear complex. / Ishizuka, Tomoya; Tobita, Kengo; Yano, Yuichi; Shiota, Yoshihito; Yoshizawa, Kazunari; Fukuzumi, Shunichi; Kojima, Takahiko.

In: Journal of the American Chemical Society, Vol. 133, No. 46, 23.11.2011, p. 18570-18573.

Research output: Contribution to journalArticle

Ishizuka, Tomoya ; Tobita, Kengo ; Yano, Yuichi ; Shiota, Yoshihito ; Yoshizawa, Kazunari ; Fukuzumi, Shunichi ; Kojima, Takahiko. / Proton-coupled electron shuttling in a covalently linked ruthenium-copper heterodinuclear complex. In: Journal of the American Chemical Society. 2011 ; Vol. 133, No. 46. pp. 18570-18573.
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