Proton transfer in hydrogen-bonded degenerate systems of water and ammonia in metal-organic frameworks

Dae Woon Lim, Masaaki Sadakiyo, Hiroshi Kitagawa

    Research output: Contribution to journalArticlepeer-review

    60 Citations (Scopus)

    Abstract

    Porous crystalline metal-organic frameworks (MOFs) or porous coordination polymers (PCPs) are emerging as a new class of proton conductors with numerous investigations. Some of the MOFs exhibit an excellent proton-conducting performance (higher than 10−2 S cm−1) originating from the interesting hydrogen(H)-bonding networks with guest molecules, where the conducting medium plays a crucial role. In the overwhelming majority of MOFs, the conducting medium is H2O because of its degenerate conjugate acid-base system (H3O+ + H2O ⇔ H2O + H3O+ or OH + H2O ⇔ H2O + OH) and the efficient H-bonding ability through two proton donor and two acceptor sites with a tetrahedral geometry. Considering the systematic molecular similarity to water, ammonia (NH3; NH4+ + NH3 ⇔ NH3 + NH4+) is promising as the next proton-conducting medium. In addition, there are few reports on NH3-mediated proton conductivity in MOFs. In this perspective, we provide overviews of the degenerate water (hydronium or hydroxide)- or ammonia (ammonium)-mediated proton conduction system, the design strategies for proton-conductive MOFs, and the conduction mechanisms.

    Original languageEnglish
    Pages (from-to)16-33
    Number of pages18
    JournalChemical Science
    Volume10
    Issue number1
    DOIs
    Publication statusPublished - 2019

    All Science Journal Classification (ASJC) codes

    • Chemistry(all)

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