Pt(II)-Catalyzed photosynthesis for H2 evolution cycling between singly and triply reduced species

Keiya Yamamoto, Kyoji Kitamoto, Kosei Yamauchi, Ken Sakai

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

A PtCl2(bpy) derivative tethered to two viologen (MV2+) moieties drives photochemical H2 evolution via forming a three-electron-reduced species possessing a bpy--based (or MV0-based) reducing equivalent. Such species can only form after one electron reduction of both the MV2+ sites because of rapid intramolecular electron transfer from bpy- to MV2+.

Original languageEnglish
Pages (from-to)14516-14519
Number of pages4
JournalChemical Communications
Volume51
Issue number77
DOIs
Publication statusPublished - Aug 4 2015

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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