Pt(II) N-confused porphyrin: An expanded pyrrole that affords a stable π-anion

Dong Hoon Won, Motoki Toganoh, Hidemitsu Uno, Hiroyuki Furuta

    Research output: Contribution to journalArticlepeer-review

    24 Citations (Scopus)

    Abstract

    Pt(II) complex of meso-tetrakis(pentafluorophenyl) N-confused porphyrin (1-Pt) efficiently binds Cl-, Br-, and I- anions at the peripheral N-H, while deprotonation proceeds with F-, H2PO4-, and OH- in CH 2Cl2 solution; neutral and anionic structures of 1-Pt were characterized by single crystal X-ray diffraction analysis.

    Original languageEnglish
    Pages (from-to)6151-6158
    Number of pages8
    JournalDalton Transactions
    Issue number31
    DOIs
    Publication statusPublished - Aug 10 2009

    All Science Journal Classification (ASJC) codes

    • Inorganic Chemistry

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