TY - JOUR
T1 - Pump - Probe photodepletion spectroscopy of (C6H6)+2. Identification of spectrum in the charge resonance band region
AU - Ohashi, Kazuhiko
AU - Inokuchi, Yoshiya
AU - Nishi, Nobuyuki
N1 - Funding Information:
This work was supporteidn part by Grant-in-Aid for researchp rograms( 07740465a nd 07454190) from the Ministryo f EducationS, cienceS, portsa nd Cultureo f Japan.F inanciasl upporftr omthe Morino
PY - 1996/12/6
Y1 - 1996/12/6
N2 - Pump - probe photodepletion (hole-burning) experiments are performed on mass-selected cluster ions in the gas phase. An electronic spectrum of (C6H6)+2 in the near-infrared region comprises two charge resonance bands at 920 and 1160 nm. The intensities of these two bands monitored by the probe laser are shown to be reduced by the same amount with the introduction of the pump laser. The behavior proves that the CR bands are due to two distinct transitions of a single isomer. No evidence is found for the existence of other isomers of (C6H6)+2.
AB - Pump - probe photodepletion (hole-burning) experiments are performed on mass-selected cluster ions in the gas phase. An electronic spectrum of (C6H6)+2 in the near-infrared region comprises two charge resonance bands at 920 and 1160 nm. The intensities of these two bands monitored by the probe laser are shown to be reduced by the same amount with the introduction of the pump laser. The behavior proves that the CR bands are due to two distinct transitions of a single isomer. No evidence is found for the existence of other isomers of (C6H6)+2.
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U2 - 10.1016/S0009-2614(96)01209-2
DO - 10.1016/S0009-2614(96)01209-2
M3 - Article
AN - SCOPUS:0030573111
SN - 0009-2614
VL - 263
SP - 167
EP - 172
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 1-2
ER -