Raman Scattering Study of Scheelite-Type Double Molybdates

Kazuhiro Hara, Hiromitsu Takenaka, Yoshihiro Ishibashi

Research output: Contribution to journalArticle

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Abstract

Raman scattering measurements were performed to investigate optical modes of scheelite-type double molybdates XY(MoO4)2 (X=Li, Na and Y = La, Nd). In the polarized Raman scattering measurements, we have found four modes in NaLa(MoO4)2, one in low frequency region (with Bg symmetry) and three in high frequency region, which are missing in the previous observation by Ramakrishnan. The scattered light by the high-frequency modes does not show clear polarization characteristics. By the drastic modification of these modes with changing the proportion x of NaxLa(4–x)/3(MoO4)2, we concluded that the newly found high-frequency modes result from the local deformation caused by the random positioning of the X+ and Y3+ ions.

Original languageEnglish
Pages (from-to)3220-3225
Number of pages6
Journaljournal of the physical society of japan
Volume57
Issue number9
DOIs
Publication statusPublished - Jan 1 1988
Externally publishedYes

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scheelite
molybdates
Raman spectra
polarization characteristics
positioning
proportion
low frequencies
symmetry
ions

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)

Cite this

Raman Scattering Study of Scheelite-Type Double Molybdates. / Hara, Kazuhiro; Takenaka, Hiromitsu; Ishibashi, Yoshihiro.

In: journal of the physical society of japan, Vol. 57, No. 9, 01.01.1988, p. 3220-3225.

Research output: Contribution to journalArticle

Hara, Kazuhiro ; Takenaka, Hiromitsu ; Ishibashi, Yoshihiro. / Raman Scattering Study of Scheelite-Type Double Molybdates. In: journal of the physical society of japan. 1988 ; Vol. 57, No. 9. pp. 3220-3225.
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