Rapid and efficient catalytic oxidation of As(III) with oxygen over a Pt catalyst at increased temperature

Jinxian Zhao, Hideki Matsune, Sakae Takenaka, Masahiro Kishida

Research output: Contribution to journalArticle

Abstract

The pre-oxidation of arsenite (As(III)) to arsenate (As(V)) is a critical step for the removal of toxic arsenic in wastewater. In this work, a Pt catalyst supported on metal oxide was applied to the pre-oxidation step of As(III) without UV irradiation. It is demonstrated that Pt catalyst can effectively promote the oxidation of As(III) using oxygen at neutral pH due to the catalytic activity of Pt itself. The Pt/ZrO2 catalyst possessed excellent stability and could be used repeatedly with high catalytic performance. The oxidation rate of As(III) was structure-insensitive to Pt particle size and obeyed pseudo-first-order kinetics in As(III). The apparent activation energy was about 31.1 kJ/mol, which was obtained on the premise of order of 0.5 with respect to oxygen.

Original languageEnglish
Pages (from-to)270-278
Number of pages9
JournalChemical Engineering Journal
Volume325
DOIs
Publication statusPublished - Jan 1 2017

Fingerprint

Catalytic oxidation
catalyst
Oxygen
oxidation
Oxidation
oxygen
Catalysts
temperature
Temperature
arsenite
Poisons
Arsenic
arsenate
Catalyst supports
activation energy
Oxides
arsenic
Catalyst activity
irradiation
Wastewater

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Environmental Chemistry
  • Chemical Engineering(all)
  • Industrial and Manufacturing Engineering

Cite this

Rapid and efficient catalytic oxidation of As(III) with oxygen over a Pt catalyst at increased temperature. / Zhao, Jinxian; Matsune, Hideki; Takenaka, Sakae; Kishida, Masahiro.

In: Chemical Engineering Journal, Vol. 325, 01.01.2017, p. 270-278.

Research output: Contribution to journalArticle

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