Abstract
Up to 154-fold rate enhancement (see picture) and higher yields are achieved with the bowl-shaped triarylphosphane ligand P(tm-tp)3 compared with common phosphane ligands in Rh-catalyzed hydrosilylation of ketones. The superior performance of P(tm-tp)3 over the similar P(tp)3 is apparently related to the deeper bowl formed by the methyl-bearing terphenyl substituents in the former.
Original language | English |
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Pages (from-to) | 1287-1289 |
Number of pages | 3 |
Journal | Angewandte Chemie - International Edition |
Volume | 42 |
Issue number | 11 |
DOIs | |
Publication status | Published - Mar 17 2003 |
Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Catalysis
- Chemistry(all)