Abstract
Up to 154-fold rate enhancement (see picture) and higher yields are achieved with the bowl-shaped triarylphosphane ligand P(tm-tp)3 compared with common phosphane ligands in Rh-catalyzed hydrosilylation of ketones. The superior performance of P(tm-tp)3 over the similar P(tp)3 is apparently related to the deeper bowl formed by the methyl-bearing terphenyl substituents in the former.
| Original language | English |
|---|---|
| Pages (from-to) | 1287-1289 |
| Number of pages | 3 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 42 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - Mar 17 2003 |
| Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Catalysis
- Chemistry(all)
Fingerprint Dive into the research topics of 'Rate enhancement with a bowl-shaped phosphane in the rhodium-catalyzed hydrosilylation of ketones'. Together they form a unique fingerprint.
Cite this
Niyomura, O., Tokunaga, M., Obora, Y., Iwasawa, T., & Tsuji, Y. (2003). Rate enhancement with a bowl-shaped phosphane in the rhodium-catalyzed hydrosilylation of ketones. Angewandte Chemie - International Edition, 42(11), 1287-1289. https://doi.org/10.1002/anie.200390331