Rational syntheses of helical π-conjugated oligopyrrins with a bipyrrole linkage: Geometry control of bis-copper(II) coordination

Kai Zhang; Mathew Savage; Xin Li; Yu Jiang; Masatoshi Ishida; Koki Mitsuno; Satoru Karasawa; Tatsuhisa Kato; Weihua Zhu; Sihai Yang; Hiroyuki Furuta; Yongshu Xie

doi:10.1039/c6cc00707d

Rational syntheses of helical π-conjugated oligopyrrins with a bipyrrole linkage: Geometry control of bis-copper(II) coordination

Kai Zhang, Mathew Savage, Xin Li, Yu Jiang, Masatoshi Ishida, Koki Mitsuno, Satoru Karasawa, Tatsuhisa Kato, Weihua Zhu, Sihai Yang, Hiroyuki Furuta, Yongshu Xie

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

A rational and effective approach for synthesizing linear π-conjugated hexa-, hepta- and octapyrrins through the regioselective oxidative coupling of monoacylated tripyrrane and bilane is described. Depending upon the numbers of pyrrolic units, the geometry and properties of bis-copper(ii) complexes could be systematically modulated.

Original language	English
Pages (from-to)	5148-5151
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	29
DOIs	https://doi.org/10.1039/c6cc00707d
Publication status	Published - 2016

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c6cc00707d

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abstract = "A rational and effective approach for synthesizing linear π-conjugated hexa-, hepta- and octapyrrins through the regioselective oxidative coupling of monoacylated tripyrrane and bilane is described. Depending upon the numbers of pyrrolic units, the geometry and properties of bis-copper(ii) complexes could be systematically modulated.",

author = "Kai Zhang and Mathew Savage and Xin Li and Yu Jiang and Masatoshi Ishida and Koki Mitsuno and Satoru Karasawa and Tatsuhisa Kato and Weihua Zhu and Sihai Yang and Hiroyuki Furuta and Yongshu Xie",

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doi = "10.1039/c6cc00707d",

language = "English",

volume = "52",

pages = "5148--5151",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Rational syntheses of helical π-conjugated oligopyrrins with a bipyrrole linkage

T2 - Geometry control of bis-copper(II) coordination

AU - Zhang, Kai

AU - Savage, Mathew

AU - Li, Xin

AU - Jiang, Yu

AU - Ishida, Masatoshi

AU - Mitsuno, Koki

AU - Karasawa, Satoru

AU - Kato, Tatsuhisa

AU - Zhu, Weihua

AU - Yang, Sihai

AU - Furuta, Hiroyuki

AU - Xie, Yongshu

PY - 2016

Y1 - 2016

N2 - A rational and effective approach for synthesizing linear π-conjugated hexa-, hepta- and octapyrrins through the regioselective oxidative coupling of monoacylated tripyrrane and bilane is described. Depending upon the numbers of pyrrolic units, the geometry and properties of bis-copper(ii) complexes could be systematically modulated.

AB - A rational and effective approach for synthesizing linear π-conjugated hexa-, hepta- and octapyrrins through the regioselective oxidative coupling of monoacylated tripyrrane and bilane is described. Depending upon the numbers of pyrrolic units, the geometry and properties of bis-copper(ii) complexes could be systematically modulated.

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U2 - 10.1039/c6cc00707d

DO - 10.1039/c6cc00707d

M3 - Article

AN - SCOPUS:84963556404

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VL - 52

SP - 5148

EP - 5151

JO - Chemical Communications

JF - Chemical Communications

IS - 29

ER -

Rational syntheses of helical π-conjugated oligopyrrins with a bipyrrole linkage: Geometry control of bis-copper(II) coordination

Abstract

All Science Journal Classification (ASJC) codes

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