Reaction of Disilylketenes with Organolithiums: New Synthetic Route to Silylacetylene Derivatives

Masato Ito; Eiji Shirakawa; Hidemasa Takaya

doi:10.1055/s-1996-5579

Reaction of Disilylketenes with Organolithiums: New Synthetic Route to Silylacetylene Derivatives

Masato Ito, Eiji Shirakawa, Hidemasa Takaya

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

α,α-Disilylenolates generated in situ from disilylketenes and organolithiums in the presence of HMPA undergo the Peterson-type elimination to give silylacetylene derivatives in moderate to good yields. Geminal disilyl substitution on ketene moiety is crucially important for the successful elimination from the corresponding α,α-disilylenolates.

Original language	English
Pages (from-to)	635-636
Number of pages	2
Journal	Synlett
Volume	1996
Issue number	7
DOIs	https://doi.org/10.1055/s-1996-5579
Publication status	Published - Jan 1 1996
Externally published	Yes

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1055/s-1996-5579

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abstract = "α,α-Disilylenolates generated in situ from disilylketenes and organolithiums in the presence of HMPA undergo the Peterson-type elimination to give silylacetylene derivatives in moderate to good yields. Geminal disilyl substitution on ketene moiety is crucially important for the successful elimination from the corresponding α,α-disilylenolates.",

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AU - Takaya, Hidemasa

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N2 - α,α-Disilylenolates generated in situ from disilylketenes and organolithiums in the presence of HMPA undergo the Peterson-type elimination to give silylacetylene derivatives in moderate to good yields. Geminal disilyl substitution on ketene moiety is crucially important for the successful elimination from the corresponding α,α-disilylenolates.

AB - α,α-Disilylenolates generated in situ from disilylketenes and organolithiums in the presence of HMPA undergo the Peterson-type elimination to give silylacetylene derivatives in moderate to good yields. Geminal disilyl substitution on ketene moiety is crucially important for the successful elimination from the corresponding α,α-disilylenolates.

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Reaction of Disilylketenes with Organolithiums: New Synthetic Route to Silylacetylene Derivatives

Abstract

All Science Journal Classification (ASJC) codes

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