Reactions involving fluoride ion part 43 1 oligomerisations of hexafluoro-1,3-butadiene and -but-2-yne

Richard D. Chambers, Shin Nishimura, Graham Sandford

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Oligomerisation of hexafluoro-1,3-butadiene (6) and hexafluorobut-2-yne (1) occur with tetrakis(dimethylamino)ethene (10), in the absence of a solvent. Hydrogen-terminated oligomers are obtained but in the presence of pentafluoropyridine (12) or tetrafluoropyrimidine (17), simple trapping products are obtained. It is concluded that the polymerisation of 6 occurs by very rapid rearrangement to 1, followed by polymerisation of the latter.

Original languageEnglish
Pages (from-to)63-68
Number of pages6
JournalJournal of Fluorine Chemistry
Volume91
Issue number1
DOIs
Publication statusPublished - Aug 10 1998
Externally publishedYes

Fingerprint

butadiene
Fluorides
polymerization
fluoride
Polymerization
fluorides
Ions
Oligomerization
ion
oligomers
Oligomers
ethylene
trapping
Hydrogen
ions
hydrogen
products
1,3-butadiene
pentafluoropyridine
product

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Environmental Chemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Reactions involving fluoride ion part 43 1 oligomerisations of hexafluoro-1,3-butadiene and -but-2-yne. / Chambers, Richard D.; Nishimura, Shin; Sandford, Graham.

In: Journal of Fluorine Chemistry, Vol. 91, No. 1, 10.08.1998, p. 63-68.

Research output: Contribution to journalArticle

@article{bc2e5eadd8f2439590a8523b49dcf576,
title = "Reactions involving fluoride ion part 43 1 oligomerisations of hexafluoro-1,3-butadiene and -but-2-yne",
abstract = "Oligomerisation of hexafluoro-1,3-butadiene (6) and hexafluorobut-2-yne (1) occur with tetrakis(dimethylamino)ethene (10), in the absence of a solvent. Hydrogen-terminated oligomers are obtained but in the presence of pentafluoropyridine (12) or tetrafluoropyrimidine (17), simple trapping products are obtained. It is concluded that the polymerisation of 6 occurs by very rapid rearrangement to 1, followed by polymerisation of the latter.",
author = "Chambers, {Richard D.} and Shin Nishimura and Graham Sandford",
year = "1998",
month = "8",
day = "10",
doi = "10.1016/S0022-1139(98)00213-9",
language = "English",
volume = "91",
pages = "63--68",
journal = "Journal of Fluorine Chemistry",
issn = "0022-1139",
publisher = "Elsevier BV",
number = "1",

}

TY - JOUR

T1 - Reactions involving fluoride ion part 43 1 oligomerisations of hexafluoro-1,3-butadiene and -but-2-yne

AU - Chambers, Richard D.

AU - Nishimura, Shin

AU - Sandford, Graham

PY - 1998/8/10

Y1 - 1998/8/10

N2 - Oligomerisation of hexafluoro-1,3-butadiene (6) and hexafluorobut-2-yne (1) occur with tetrakis(dimethylamino)ethene (10), in the absence of a solvent. Hydrogen-terminated oligomers are obtained but in the presence of pentafluoropyridine (12) or tetrafluoropyrimidine (17), simple trapping products are obtained. It is concluded that the polymerisation of 6 occurs by very rapid rearrangement to 1, followed by polymerisation of the latter.

AB - Oligomerisation of hexafluoro-1,3-butadiene (6) and hexafluorobut-2-yne (1) occur with tetrakis(dimethylamino)ethene (10), in the absence of a solvent. Hydrogen-terminated oligomers are obtained but in the presence of pentafluoropyridine (12) or tetrafluoropyrimidine (17), simple trapping products are obtained. It is concluded that the polymerisation of 6 occurs by very rapid rearrangement to 1, followed by polymerisation of the latter.

UR - http://www.scopus.com/inward/record.url?scp=0032504329&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0032504329&partnerID=8YFLogxK

U2 - 10.1016/S0022-1139(98)00213-9

DO - 10.1016/S0022-1139(98)00213-9

M3 - Article

AN - SCOPUS:0032504329

VL - 91

SP - 63

EP - 68

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

SN - 0022-1139

IS - 1

ER -