Rearrangements of a [36]octaphyrin triggered by nickel(II) metalation: Metamorphosis to a directly meso-β-linked diporphyrin

Yasuo Tanaka; Hirotaka Mori; Taro Koide; Hideki Yorimitsu; Naoki Aratani; Atsuhiro Osuka

doi:10.1002/anie.201105809

Rearrangements of a [36]octaphyrin triggered by nickel(II) metalation: Metamorphosis to a directly meso-β-linked diporphyrin

Yasuo Tanaka, Hirotaka Mori, Taro Koide, Hideki Yorimitsu, Naoki Aratani, Atsuhiro Osuka

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

Breaking and entering: A figure-of-eight dinickel(II) complex and skeletal rearrangement products including a pyrrole-ring-cleaved product, a directly meso-β-linked diporphyrin (see scheme), and a dearylative oxygenation product have been formed in moderate yields by a nickel(II) metalation of [36]octaphyrin(1.1.1.1.1.1.1.1) in acetonitrile.

Original language	English
Pages (from-to)	11460-11464
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	48
DOIs	https://doi.org/10.1002/anie.201105809
Publication status	Published - Nov 25 2011
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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10.1002/anie.201105809

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Rearrangements of a [36]octaphyrin triggered by nickel(II) metalation : Metamorphosis to a directly meso-β-linked diporphyrin. / Tanaka, Yasuo; Mori, Hirotaka; Koide, Taro; Yorimitsu, Hideki; Aratani, Naoki; Osuka, Atsuhiro.

In: Angewandte Chemie - International Edition, Vol. 50, No. 48, 25.11.2011, p. 11460-11464.

Research output: Contribution to journal › Article › peer-review

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