TY - JOUR
T1 - Rearrangements of a [36]octaphyrin triggered by nickel(II) metalation
T2 - Metamorphosis to a directly meso-β-linked diporphyrin
AU - Tanaka, Yasuo
AU - Mori, Hirotaka
AU - Koide, Taro
AU - Yorimitsu, Hideki
AU - Aratani, Naoki
AU - Osuka, Atsuhiro
N1 - Copyright:
Copyright 2011 Elsevier B.V., All rights reserved.
PY - 2011/11/25
Y1 - 2011/11/25
N2 - Breaking and entering: A figure-of-eight dinickel(II) complex and skeletal rearrangement products including a pyrrole-ring-cleaved product, a directly meso-β-linked diporphyrin (see scheme), and a dearylative oxygenation product have been formed in moderate yields by a nickel(II) metalation of [36]octaphyrin(1.1.1.1.1.1.1.1) in acetonitrile.
AB - Breaking and entering: A figure-of-eight dinickel(II) complex and skeletal rearrangement products including a pyrrole-ring-cleaved product, a directly meso-β-linked diporphyrin (see scheme), and a dearylative oxygenation product have been formed in moderate yields by a nickel(II) metalation of [36]octaphyrin(1.1.1.1.1.1.1.1) in acetonitrile.
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U2 - 10.1002/anie.201105809
DO - 10.1002/anie.201105809
M3 - Article
C2 - 21976175
AN - SCOPUS:81755177748
VL - 50
SP - 11460
EP - 11464
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 48
ER -