Abstract
Breaking and entering: A figure-of-eight dinickel(II) complex and skeletal rearrangement products including a pyrrole-ring-cleaved product, a directly meso-β-linked diporphyrin (see scheme), and a dearylative oxygenation product have been formed in moderate yields by a nickel(II) metalation of [36]octaphyrin(1.1.1.1.1.1.1.1) in acetonitrile.
| Original language | English |
|---|---|
| Pages (from-to) | 11460-11464 |
| Number of pages | 5 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 50 |
| Issue number | 48 |
| DOIs | |
| Publication status | Published - Nov 25 2011 |
| Externally published | Yes |
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All Science Journal Classification (ASJC) codes
- Catalysis
- Chemistry(all)
Cite this
Rearrangements of a [36]octaphyrin triggered by nickel(II) metalation : Metamorphosis to a directly meso-β-linked diporphyrin. / Tanaka, Yasuo; Mori, Hirotaka; Koide, Taro; Yorimitsu, Hideki; Aratani, Naoki; Osuka, Atsuhiro.
In: Angewandte Chemie - International Edition, Vol. 50, No. 48, 25.11.2011, p. 11460-11464.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Rearrangements of a [36]octaphyrin triggered by nickel(II) metalation
T2 - Metamorphosis to a directly meso-β-linked diporphyrin
AU - Tanaka, Yasuo
AU - Mori, Hirotaka
AU - Koide, Taro
AU - Yorimitsu, Hideki
AU - Aratani, Naoki
AU - Osuka, Atsuhiro
PY - 2011/11/25
Y1 - 2011/11/25
N2 - Breaking and entering: A figure-of-eight dinickel(II) complex and skeletal rearrangement products including a pyrrole-ring-cleaved product, a directly meso-β-linked diporphyrin (see scheme), and a dearylative oxygenation product have been formed in moderate yields by a nickel(II) metalation of [36]octaphyrin(1.1.1.1.1.1.1.1) in acetonitrile.
AB - Breaking and entering: A figure-of-eight dinickel(II) complex and skeletal rearrangement products including a pyrrole-ring-cleaved product, a directly meso-β-linked diporphyrin (see scheme), and a dearylative oxygenation product have been formed in moderate yields by a nickel(II) metalation of [36]octaphyrin(1.1.1.1.1.1.1.1) in acetonitrile.
UR - http://www.scopus.com/inward/record.url?scp=81755177748&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=81755177748&partnerID=8YFLogxK
U2 - 10.1002/anie.201105809
DO - 10.1002/anie.201105809
M3 - Article
C2 - 21976175
AN - SCOPUS:81755177748
VL - 50
SP - 11460
EP - 11464
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 48
ER -