Rearrangements of a [36]octaphyrin triggered by nickel(II) metalation: Metamorphosis to a directly meso-β-linked diporphyrin

Yasuo Tanaka, Hirotaka Mori, Taro Koide, Hideki Yorimitsu, Naoki Aratani, Atsuhiro Osuka

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

Breaking and entering: A figure-of-eight dinickel(II) complex and skeletal rearrangement products including a pyrrole-ring-cleaved product, a directly meso-β-linked diporphyrin (see scheme), and a dearylative oxygenation product have been formed in moderate yields by a nickel(II) metalation of [36]octaphyrin(1.1.1.1.1.1.1.1) in acetonitrile.

Original languageEnglish
Pages (from-to)11460-11464
Number of pages5
JournalAngewandte Chemie - International Edition
Volume50
Issue number48
DOIs
Publication statusPublished - Nov 25 2011
Externally publishedYes

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Pyrroles
Oxygenation
Nickel
Acetonitrile
acetonitrile

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Rearrangements of a [36]octaphyrin triggered by nickel(II) metalation : Metamorphosis to a directly meso-β-linked diporphyrin. / Tanaka, Yasuo; Mori, Hirotaka; Koide, Taro; Yorimitsu, Hideki; Aratani, Naoki; Osuka, Atsuhiro.

In: Angewandte Chemie - International Edition, Vol. 50, No. 48, 25.11.2011, p. 11460-11464.

Research output: Contribution to journalArticle

Tanaka, Yasuo ; Mori, Hirotaka ; Koide, Taro ; Yorimitsu, Hideki ; Aratani, Naoki ; Osuka, Atsuhiro. / Rearrangements of a [36]octaphyrin triggered by nickel(II) metalation : Metamorphosis to a directly meso-β-linked diporphyrin. In: Angewandte Chemie - International Edition. 2011 ; Vol. 50, No. 48. pp. 11460-11464.
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