Recent advances in multireference-based perturbation theory

Haruyuki Nakano, Kimihiko Hirao

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Accurate ab initio computational chemistry has evolved dramatically. In particular, the development of multireference-based approaches has opened up a completely new area, and has had a profound impact on the potential of theoretical chemistry. Multireference-based perturbation theory (MRPT) is an extension of the closed-shell single reference Møller-Plesset method, and has been successfully applied to many chemical and spectroscopic problems. MRPT has established itself as an efficient technique for treating nondynamical and dynamical correlations. Usually, a complete active space self-consistent field (CASSCF) wave function is chosen as a reference function of MRPT. However, CASSCF often generates too many configurations, and the size of the active space can outgrow the capacity of the present technology. Many attempts have been proposed to reduce the dimension of CASSCF and to widen the range of applications of MRPT. This review focuses on our recent development in MRPT.

Original languageEnglish
Pages (from-to)812-816
Number of pages5
JournalBulletin of the Korean Chemical Society
Volume24
Issue number6
DOIs
Publication statusPublished - Jun 20 2003
Externally publishedYes

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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