Recent progress in photon upconverting gels

Pankaj Bharmoria, Nobuhiro Yanai, Nobuo Kimizuka

Research output: Contribution to journalReview article

1 Citation (Scopus)

Abstract

Recent progress in the development of gels showing triplet-triplet annihilation based photon upconversion (TTA-UC) is reviewed. Among the two families of upconverting gels reported, those display TTA-UC based on molecular diffusion show performances comparable to those in solutions, and the TTA-UC therein are affected by dissolved molecular oxygen. Meanwhile, air-stable TTA-UC is achieved in organogels and hydrogels by suitably accumulating TTA-UC chromophores which are stabilized by hydrogen bonding networks of the gelators. The unique feature of the air-stable upconverting gels is that the self-assembled nanostructures are protected from molecular oxygen dissolved in the microscopically interconnected solution phase. The presence of the bicontinuous structures formed by the upconverting fibrous nanoassemblies and the solution phase is utilized to design photochemical reaction systems induced by TTA-UC. Future challenges include in vivo applications of hydrogels showing near infrared-to-visible TTA-UC.

Original languageEnglish
Article number18
JournalGels
Volume5
Issue number1
DOIs
Publication statusPublished - Mar 1 2019

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Gels
Photons
Hydrogels
Molecular oxygen
Photochemical reactions
Dissolved oxygen
Chromophores
Air
Nanostructures
Hydrogen bonds
Infrared radiation

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Bioengineering
  • Biomaterials
  • Polymers and Plastics

Cite this

Recent progress in photon upconverting gels. / Bharmoria, Pankaj; Yanai, Nobuhiro; Kimizuka, Nobuo.

In: Gels, Vol. 5, No. 1, 18, 01.03.2019.

Research output: Contribution to journalReview article

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