TY - JOUR
T1 - Redox stability of metal-supported fuel cells with nickel/gadolinium-doped ceria anode
AU - Thaler, Florian
AU - Udomsilp, David
AU - Schafbauer, Wolfgang
AU - Bischof, Cornelia
AU - Fukuyama, Yosuke
AU - Miura, Yohei
AU - Kawabuchi, Mari
AU - Taniguchi, Shunsuke
AU - Takemiya, Satoshi
AU - Nenning, Andreas
AU - Opitz, Alexander Karl
AU - Bram, Martin
N1 - Funding Information:
The Christian Doppler Laboratories are funded in equal measure by the public authorities and the companies directly involved in the laboratories. We are very grateful for the funding provided by the Austrian Federal Ministry for Digital and Economic Affairs (BMDW) and the industrial partners Plansee SE and AVL List GmbH.
Publisher Copyright:
© 2019 Elsevier B.V.
PY - 2019/9/15
Y1 - 2019/9/15
N2 - Metal-supported fuel cells (MSCs) are promising candidates for not only stationary but also mobile applications. Their appeal is in their potential to withstand reoxidation of the anode, which might occur by an interruption of the fuel supply or an emergency shutdown of the fuel cell system. A novel nickel/gadolinium-doped ceria anode (Ni/GDC) was recently introduced in a MSC concept of Plansee, almost doubling power density compared to cells with a nickel/yttria-doped zirconia (Ni/YSZ) anode. In this study, both cell concepts are compared concerning their ability to tolerate harsh redox cycles. Therefore, controlled redox cycles of the anodes were conducted at different temperatures. The response of the cell's power output to the redox cycling experiments was continuously recorded. In the case of MSCs with a Ni/YSZ anode, strong degradation occurs after redox cycling. In contrast, cells with a Ni/GDC anode exhibit significantly improved redox tolerance and cell performance improves with the number of redox cycles. For understanding this behavior, microstructural investigations of the Ni/GDC anode and the adjacent electrolyte were performed by FIB-SEM. The long-term redox behavior of MSCs with a Ni/GDC anode was also investigated by conducting more comprehensive redox cycles at 400 °C, 500 °C, and 600 °C.
AB - Metal-supported fuel cells (MSCs) are promising candidates for not only stationary but also mobile applications. Their appeal is in their potential to withstand reoxidation of the anode, which might occur by an interruption of the fuel supply or an emergency shutdown of the fuel cell system. A novel nickel/gadolinium-doped ceria anode (Ni/GDC) was recently introduced in a MSC concept of Plansee, almost doubling power density compared to cells with a nickel/yttria-doped zirconia (Ni/YSZ) anode. In this study, both cell concepts are compared concerning their ability to tolerate harsh redox cycles. Therefore, controlled redox cycles of the anodes were conducted at different temperatures. The response of the cell's power output to the redox cycling experiments was continuously recorded. In the case of MSCs with a Ni/YSZ anode, strong degradation occurs after redox cycling. In contrast, cells with a Ni/GDC anode exhibit significantly improved redox tolerance and cell performance improves with the number of redox cycles. For understanding this behavior, microstructural investigations of the Ni/GDC anode and the adjacent electrolyte were performed by FIB-SEM. The long-term redox behavior of MSCs with a Ni/GDC anode was also investigated by conducting more comprehensive redox cycles at 400 °C, 500 °C, and 600 °C.
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U2 - 10.1016/j.jpowsour.2019.226751
DO - 10.1016/j.jpowsour.2019.226751
M3 - Article
AN - SCOPUS:85067785131
VL - 434
JO - Journal of Power Sources
JF - Journal of Power Sources
SN - 0378-7753
M1 - 226751
ER -