Redox-switched crown ethers monocrown-biscrown interconversion coupled with redox of a thiol-disulfide couple

Takahide Minami, Seiji Shinkai, Osamu Manabe

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

To give a redox-switch function to crown ethers, 4′-mercaptomono-benzo-15-crown-5 (CrSH) and its oxidized disulfide form (CrSSCr) were synthesized. The solvent extraction proved that the ion affinity of CrSH is generally greater than that of CrSSCr.

Original languageEnglish
Pages (from-to)5167-5170
Number of pages4
JournalTetrahedron Letters
Volume23
Issue number49
DOIs
Publication statusPublished - Jan 1 1982
Externally publishedYes

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Crown Ethers
Solvent extraction
Sulfhydryl Compounds
Disulfides
Oxidation-Reduction
Switches
Ions
15-crown-5

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Redox-switched crown ethers monocrown-biscrown interconversion coupled with redox of a thiol-disulfide couple. / Minami, Takahide; Shinkai, Seiji; Manabe, Osamu.

In: Tetrahedron Letters, Vol. 23, No. 49, 01.01.1982, p. 5167-5170.

Research output: Contribution to journalArticle

Minami, Takahide ; Shinkai, Seiji ; Manabe, Osamu. / Redox-switched crown ethers monocrown-biscrown interconversion coupled with redox of a thiol-disulfide couple. In: Tetrahedron Letters. 1982 ; Vol. 23, No. 49. pp. 5167-5170.
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