Reduction equilibria at the final stage of reduction of quaternary calcium ferrite with CO-CO2 gas mixtures

Takayuki Maeda, Yoichi Ono

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14 Citations (Scopus)

Abstract

Quaternary calcium ferrite was synthesized from chemical reagents of Fe2O3, CaCO3, SiO2, and Al2O3 and reduction equilibria at the final stage of reduction with CO-CO2 gas mixtures were studied. Dicalcium ferrite, which is produced during the reduction of binary calcium ferrite, is not found in the reduction of quaternary calcium ferrite. The reduction stage from dicalcium ferrite to iron and CaO is therefore not existent in the reduction. The reaction at the final stage of carbon monoxide reduction is given by equation 'FeO'(s)+CO(g) = Fe(s)+CO2(g) where 'FeO' is the wustite which contains CaO, SiO2 and Al2O3 as solid solutions. The temperature dependence of the apparent equilibrium constant K(=PCO(2)/PCO) of the reaction is given by the equation K=exp(-2.785 + 2,042/T) ± 0.003 (1,073-1,326 K).

Original languageEnglish
Pages (from-to)416-423
Number of pages8
JournalTetsu-To-Hagane/Journal of the Iron and Steel Institute of Japan
Volume75
Issue number3
DOIs
Publication statusPublished - Jan 1 1989

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Carbon Monoxide
Gas mixtures
gas mixtures
Ferrite
calcium
ferrites
Calcium
Equilibrium constants
Carbon monoxide
carbon monoxide
reagents
Solid solutions
solid solutions
Iron
iron
temperature dependence

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Metals and Alloys
  • Materials Chemistry

Cite this

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title = "Reduction equilibria at the final stage of reduction of quaternary calcium ferrite with CO-CO2 gas mixtures",
abstract = "Quaternary calcium ferrite was synthesized from chemical reagents of Fe2O3, CaCO3, SiO2, and Al2O3 and reduction equilibria at the final stage of reduction with CO-CO2 gas mixtures were studied. Dicalcium ferrite, which is produced during the reduction of binary calcium ferrite, is not found in the reduction of quaternary calcium ferrite. The reduction stage from dicalcium ferrite to iron and CaO is therefore not existent in the reduction. The reaction at the final stage of carbon monoxide reduction is given by equation 'FeO'(s)+CO(g) = Fe(s)+CO2(g) where 'FeO' is the wustite which contains CaO, SiO2 and Al2O3 as solid solutions. The temperature dependence of the apparent equilibrium constant K(=PCO(2)/PCO) of the reaction is given by the equation K=exp(-2.785 + 2,042/T) ± 0.003 (1,073-1,326 K).",
author = "Takayuki Maeda and Yoichi Ono",
year = "1989",
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doi = "10.2355/tetsutohagane1955.75.3_416",
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T1 - Reduction equilibria at the final stage of reduction of quaternary calcium ferrite with CO-CO2 gas mixtures

AU - Maeda, Takayuki

AU - Ono, Yoichi

PY - 1989/1/1

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N2 - Quaternary calcium ferrite was synthesized from chemical reagents of Fe2O3, CaCO3, SiO2, and Al2O3 and reduction equilibria at the final stage of reduction with CO-CO2 gas mixtures were studied. Dicalcium ferrite, which is produced during the reduction of binary calcium ferrite, is not found in the reduction of quaternary calcium ferrite. The reduction stage from dicalcium ferrite to iron and CaO is therefore not existent in the reduction. The reaction at the final stage of carbon monoxide reduction is given by equation 'FeO'(s)+CO(g) = Fe(s)+CO2(g) where 'FeO' is the wustite which contains CaO, SiO2 and Al2O3 as solid solutions. The temperature dependence of the apparent equilibrium constant K(=PCO(2)/PCO) of the reaction is given by the equation K=exp(-2.785 + 2,042/T) ± 0.003 (1,073-1,326 K).

AB - Quaternary calcium ferrite was synthesized from chemical reagents of Fe2O3, CaCO3, SiO2, and Al2O3 and reduction equilibria at the final stage of reduction with CO-CO2 gas mixtures were studied. Dicalcium ferrite, which is produced during the reduction of binary calcium ferrite, is not found in the reduction of quaternary calcium ferrite. The reduction stage from dicalcium ferrite to iron and CaO is therefore not existent in the reduction. The reaction at the final stage of carbon monoxide reduction is given by equation 'FeO'(s)+CO(g) = Fe(s)+CO2(g) where 'FeO' is the wustite which contains CaO, SiO2 and Al2O3 as solid solutions. The temperature dependence of the apparent equilibrium constant K(=PCO(2)/PCO) of the reaction is given by the equation K=exp(-2.785 + 2,042/T) ± 0.003 (1,073-1,326 K).

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