Reduction of carbon dioxide to graphite carbon via methane by catalytic fixation with membrane reactor

Hiroyasu Nishiguchi; Akira Fukunaga; Yumi Miyashita; Tatsumi Ishihara; Yusaku Takita

doi:10.1016/s0167-2991(98)80735-0

Reduction of carbon dioxide to graphite carbon via methane by catalytic fixation with membrane reactor

Hiroyasu Nishiguchi, Akira Fukunaga, Yumi Miyashita, Tatsumi Ishihara, Yusaku Takita

Research output: Contribution to journal › Article › peer-review

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Abstract

Catalytic fixation of CO₂ to graphite carbon in the temperature range above 500°C was investigated with membrane reactor. The process investigated in this study was consisted of two stage reaction, i. e., decomposition of CH₄, into C and H₂ and CO₂ methanation with formed H₂. Thus formed CH₄ from CO₂ was fed to first bed reactor to decompose to graphite carbon. It became evident that nickel supported on SiO₂ was active for both reactions. Since the decomposition of CH₄ was drastically increased with the application of membrane reactor system which considered of Pd alloy tube to CH₄ decomposition. As a result, about 70% of CO₂ can be reduced to graphite carbon at 500°C in this system. Furthermore, the high activity of catalyst was stably sustained over long period.

Original language	English
Pages (from-to)	147-152
Number of pages	6
Journal	Studies in Surface Science and Catalysis
Volume	114
DOIs	https://doi.org/10.1016/s0167-2991(98)80735-0
Publication status	Published - 1998
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Condensed Matter Physics
Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

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10.1016/s0167-2991(98)80735-0

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title = "Reduction of carbon dioxide to graphite carbon via methane by catalytic fixation with membrane reactor",

abstract = "Catalytic fixation of CO2 to graphite carbon in the temperature range above 500°C was investigated with membrane reactor. The process investigated in this study was consisted of two stage reaction, i. e., decomposition of CH4, into C and H2 and CO2 methanation with formed H2. Thus formed CH4 from CO2 was fed to first bed reactor to decompose to graphite carbon. It became evident that nickel supported on SiO2 was active for both reactions. Since the decomposition of CH4 was drastically increased with the application of membrane reactor system which considered of Pd alloy tube to CH4 decomposition. As a result, about 70% of CO2 can be reduced to graphite carbon at 500°C in this system. Furthermore, the high activity of catalyst was stably sustained over long period.",

author = "Hiroyasu Nishiguchi and Akira Fukunaga and Yumi Miyashita and Tatsumi Ishihara and Yusaku Takita",

year = "1998",

doi = "10.1016/s0167-2991(98)80735-0",

language = "English",

volume = "114",

pages = "147--152",

journal = "Studies in Surface Science and Catalysis",

issn = "0167-2991",

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TY - JOUR

T1 - Reduction of carbon dioxide to graphite carbon via methane by catalytic fixation with membrane reactor

AU - Nishiguchi, Hiroyasu

AU - Fukunaga, Akira

AU - Miyashita, Yumi

AU - Ishihara, Tatsumi

AU - Takita, Yusaku

PY - 1998

Y1 - 1998

N2 - Catalytic fixation of CO2 to graphite carbon in the temperature range above 500°C was investigated with membrane reactor. The process investigated in this study was consisted of two stage reaction, i. e., decomposition of CH4, into C and H2 and CO2 methanation with formed H2. Thus formed CH4 from CO2 was fed to first bed reactor to decompose to graphite carbon. It became evident that nickel supported on SiO2 was active for both reactions. Since the decomposition of CH4 was drastically increased with the application of membrane reactor system which considered of Pd alloy tube to CH4 decomposition. As a result, about 70% of CO2 can be reduced to graphite carbon at 500°C in this system. Furthermore, the high activity of catalyst was stably sustained over long period.

AB - Catalytic fixation of CO2 to graphite carbon in the temperature range above 500°C was investigated with membrane reactor. The process investigated in this study was consisted of two stage reaction, i. e., decomposition of CH4, into C and H2 and CO2 methanation with formed H2. Thus formed CH4 from CO2 was fed to first bed reactor to decompose to graphite carbon. It became evident that nickel supported on SiO2 was active for both reactions. Since the decomposition of CH4 was drastically increased with the application of membrane reactor system which considered of Pd alloy tube to CH4 decomposition. As a result, about 70% of CO2 can be reduced to graphite carbon at 500°C in this system. Furthermore, the high activity of catalyst was stably sustained over long period.

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JO - Studies in Surface Science and Catalysis

JF - Studies in Surface Science and Catalysis

ER -

Reduction of carbon dioxide to graphite carbon via methane by catalytic fixation with membrane reactor

Abstract

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