Reduction of dioxygen by an NADH model compound and 1,1′- dimethylferrocene catalysed by acids in homogeneous and heterogeneous systems

Shunichi Fukuzumi, Makoto Chiba, Masashi Ishikawa, Kunio Ishikawa, Toshio Tanaka

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

An acid-stable NADH model compound, 10-methyl-9,10-dihydroacridine (AcrH2) and 1,1′-dimethylferrocene [Fe(C5H 4Me)2] are oxidized by dioxygen in the presence of HClO4, in acetonitrile and water. The acid-catalysed two-electron and four-electron reductions of dioxygen by AcrH2 and [Fe(C 5H4Me)2], respectively, take place more efficiently in the heterogeneous systems using solid acid catalysts [alumina, silica-alumina, HY-type zeolite, and solid superacids (ZrO2 and Fe2O3 treated with H2SO4)] activated by calcination at various temperatures. Mechanisms of both the homogeneous and heterogeneous reduction of dioxygen by AcrH2 and [Fe(C 5H4Me)2] are discussed.

Original languageEnglish
Pages (from-to)1417-1423
Number of pages7
JournalJournal of the Chemical Society, Perkin Transactions 2
Issue number10
Publication statusPublished - Dec 1 1989

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NAD
Aluminum Oxide
Oxygen
Acids
Zeolites
Electrons
Silicon Dioxide
Calcination
Catalysts
Water
Temperature
acetonitrile
10-methyl-9,10-dihydroacridine

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Reduction of dioxygen by an NADH model compound and 1,1′- dimethylferrocene catalysed by acids in homogeneous and heterogeneous systems. / Fukuzumi, Shunichi; Chiba, Makoto; Ishikawa, Masashi; Ishikawa, Kunio; Tanaka, Toshio.

In: Journal of the Chemical Society, Perkin Transactions 2, No. 10, 01.12.1989, p. 1417-1423.

Research output: Contribution to journalArticle

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AU - Tanaka, Toshio

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