Abstract
An asymmetric monoborylation of alkenylsilanes catalyzed by a copper(I) complex with the chiral bisphosphine ligand BenzP* is reported. The reaction proceeded with excellent regioselectivity and high enantioselectivity to afford the corresponding optically active organoboronate esters with a stereogenic C-B bond containing a vicinal silyl group. The synthetic utility of the product is demonstrated through stepwise transformations to multifunctional optically active compounds in a stereospecific manner.
Original language | English |
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Pages (from-to) | 3527-3531 |
Number of pages | 5 |
Journal | Advanced Synthesis and Catalysis |
Volume | 355 |
Issue number | 18 |
DOIs | |
Publication status | Published - Dec 16 2013 |
Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Catalysis
- Organic Chemistry