Regioregular, head to tail coupled, amine functionalized polythiophenes

Paul C. Ewbank, Guido Nuding, Hikaro Suenaga, Richard D. McCullough, Seiji Shinkai

Research output: Contribution to journalConference articlepeer-review

Abstract

Regioregular, head to tail (HT) coupled poly-3-(substituted)thiophenes (PTs) were investigated. Polythiophenes with short (or no) substituents are insoluble. To circumvent this difficulty, a solubility conferring protecting group was installed on the amine. Monomer 4 was polymerized to yield a predominantly insoluble product. Monomer 6 was polymerized to yield a CHCl3 soluble material that is difficult to purify. Results showed that these materials provide convenient starting points for further modification and possess chemosensory properties.

Original languageEnglish
JournalAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume40
Issue number2
Publication statusPublished - Jan 1 1999
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics

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