Regioselective hydroxylation of the xylyl linker in a diiron(III) complex having a carboxylate-rich ligand with H2O2

Hideki Furutachi; Mizue Murayama; Amane Shiohara; Satoshi Yamazaki; Shuhei Fujinami; Akira Uehara; Masatatsu Suzuki; Seiji Ogo; Yoshihito Watanabe; Yonezo Maeda

doi:10.1039/b304171a

Regioselective hydroxylation of the xylyl linker in a diiron(III) complex having a carboxylate-rich ligand with H₂O₂

Hideki Furutachi, Mizue Murayama, Amane Shiohara, Satoshi Yamazaki, Shuhei Fujinami, Akira Uehara, Masatatsu Suzuki, Seiji Ogo, Yoshihito Watanabe, Yonezo Maeda

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Reaction of a diiron(III) complex having a xylta⁴⁻ ligand (N, N, N′, N′-m-xylylenediamine tetraacetate) with H₂O₂ resulted in regioselective hydroxylation of the m-xylyl linker. The reaction mimics the self-hydroxylation of a phenylalanine side chain found for ribonucleotide reductase (R2-W48F/D84E).

Original language	English
Pages (from-to)	1900-1901
Number of pages	2
Journal	Chemical Communications
Volume	3
Issue number	15
DOIs	https://doi.org/10.1039/b304171a
Publication status	Published - 2003
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b304171a

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Regioselective hydroxylation of the xylyl linker in a diiron(III) complex having a carboxylate-rich ligand with H₂O₂. / Furutachi, Hideki; Murayama, Mizue; Shiohara, Amane; Yamazaki, Satoshi; Fujinami, Shuhei; Uehara, Akira; Suzuki, Masatatsu; Ogo, Seiji; Watanabe, Yoshihito; Maeda, Yonezo.

In: Chemical Communications, Vol. 3, No. 15, 2003, p. 1900-1901.

Research output: Contribution to journal › Article › peer-review

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abstract = "Reaction of a diiron(III) complex having a xylta4− ligand (N, N, N′, N′-m-xylylenediamine tetraacetate) with H2O2 resulted in regioselective hydroxylation of the m-xylyl linker. The reaction mimics the self-hydroxylation of a phenylalanine side chain found for ribonucleotide reductase (R2-W48F/D84E).",

author = "Hideki Furutachi and Mizue Murayama and Amane Shiohara and Satoshi Yamazaki and Shuhei Fujinami and Akira Uehara and Masatatsu Suzuki and Seiji Ogo and Yoshihito Watanabe and Yonezo Maeda",

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AU - Shiohara, Amane

AU - Yamazaki, Satoshi

AU - Fujinami, Shuhei

AU - Uehara, Akira

AU - Suzuki, Masatatsu

AU - Ogo, Seiji

AU - Watanabe, Yoshihito

AU - Maeda, Yonezo

PY - 2003

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