Regioselective hydroxylation of the xylyl linker in a diiron(III) complex having a carboxylate-rich ligand with H2O2

Hideki Furutachi; Mizue Murayama; Amane Shiohara; Satoshi Yamazaki; Shuhei Fujinami; Akira Uehara; Masatatsu Suzuki; Seiji Ogo; Yoshihito Watanabe; Yonezo Maeda

doi:10.1039/b304171a

Regioselective hydroxylation of the xylyl linker in a diiron(III) complex having a carboxylate-rich ligand with H₂O₂

Hideki Furutachi, Mizue Murayama, Amane Shiohara, Satoshi Yamazaki, Shuhei Fujinami, Akira Uehara, Masatatsu Suzuki, Seiji Ogo, Yoshihito Watanabe, Yonezo Maeda

Research output: Contribution to journal › Article

18 Citations (Scopus)

Abstract

Reaction of a diiron(III) complex having a xylta⁴⁻ ligand (N, N, N′, N′-m-xylylenediamine tetraacetate) with H₂O₂ resulted in regioselective hydroxylation of the m-xylyl linker. The reaction mimics the self-hydroxylation of a phenylalanine side chain found for ribonucleotide reductase (R2-W48F/D84E).

Original language	English
Pages (from-to)	1900-1901
Number of pages	2
Journal	Chemical Communications
Volume	3
Issue number	15
DOIs	https://doi.org/10.1039/b304171a
Publication status	Published - Jan 1 2003
Externally published	Yes

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All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

Furutachi, H., Murayama, M., Shiohara, A., Yamazaki, S., Fujinami, S., Uehara, A., ... Maeda, Y. (2003). Regioselective hydroxylation of the xylyl linker in a diiron(III) complex having a carboxylate-rich ligand with H₂O₂. Chemical Communications, 3(15), 1900-1901. https://doi.org/10.1039/b304171a

Regioselective hydroxylation of the xylyl linker in a diiron(III) complex having a carboxylate-rich ligand with H₂O₂. / Furutachi, Hideki; Murayama, Mizue; Shiohara, Amane; Yamazaki, Satoshi; Fujinami, Shuhei; Uehara, Akira; Suzuki, Masatatsu; Ogo, Seiji; Watanabe, Yoshihito; Maeda, Yonezo.

In: Chemical Communications, Vol. 3, No. 15, 01.01.2003, p. 1900-1901.

Research output: Contribution to journal › Article

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abstract = "Reaction of a diiron(III) complex having a xylta4− ligand (N, N, N′, N′-m-xylylenediamine tetraacetate) with H2O2 resulted in regioselective hydroxylation of the m-xylyl linker. The reaction mimics the self-hydroxylation of a phenylalanine side chain found for ribonucleotide reductase (R2-W48F/D84E).",

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AU - Yamazaki, Satoshi

AU - Fujinami, Shuhei

AU - Uehara, Akira

AU - Suzuki, Masatatsu

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10.1039/b304171a