Regioselective lactonization of unsymmetrical 1,4-diols: An efficient access to lactone lignans

Masato Ito, Akira Shiibashi, Takao Ikariya

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

A Cp*Ru-based bifunctional catalyst system (Cp* = η5-C5(CH3)5) with a suitably-designed PN ligand (PN = chelating tertiary phosphine-protic amine ligand) has been developed for a regioselective lactonization of unsymmetrically substituted 1,4-diols, which may provide an expeditious access to a variety of lactone lignans.

Original languageEnglish
Pages (from-to)2134-2136
Number of pages3
JournalChemical Communications
Volume47
Issue number7
DOIs
Publication statusPublished - Feb 21 2011

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Lignans
phosphine
Lactones
Ligands
Chelation
Amines
Catalysts

All Science Journal Classification (ASJC) codes

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Regioselective lactonization of unsymmetrical 1,4-diols : An efficient access to lactone lignans. / Ito, Masato; Shiibashi, Akira; Ikariya, Takao.

In: Chemical Communications, Vol. 47, No. 7, 21.02.2011, p. 2134-2136.

Research output: Contribution to journalArticle

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