Regioselective nucleophilic substitution reaction of meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin

Masaaki Suzuki, Soji Shimizu, Ji Young Shin, Atsuhiro Osuka

Research output: Contribution to journalArticle

49 Citations (Scopus)

Abstract

Reaction of various alkoxides led to the selective replacement of the p-fluorine substituents of meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin. Reaction with isopropyl amine gave meso-hexakis(4-isopropylamino-2,3,5,6-tetrafluorophenyl) substituted [28]hexaphyrin.

Original languageEnglish
Pages (from-to)4597-4601
Number of pages5
JournalTetrahedron Letters
Volume44
Issue number24
DOIs
Publication statusPublished - Jun 9 2003
Externally publishedYes

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Fluorine
Amines
Substitution reactions

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Regioselective nucleophilic substitution reaction of meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin. / Suzuki, Masaaki; Shimizu, Soji; Shin, Ji Young; Osuka, Atsuhiro.

In: Tetrahedron Letters, Vol. 44, No. 24, 09.06.2003, p. 4597-4601.

Research output: Contribution to journalArticle

Suzuki, Masaaki ; Shimizu, Soji ; Shin, Ji Young ; Osuka, Atsuhiro. / Regioselective nucleophilic substitution reaction of meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin. In: Tetrahedron Letters. 2003 ; Vol. 44, No. 24. pp. 4597-4601.
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