Regulation of a cerium(iv)-driven O2 evolution reaction using composites of liposome and lipophilic ruthenium complexes

Tomomi Koshiyama, Nao Kanda, Koki Iwata, Masayuki Honjo, Sana Asada, Tatsuru Hatae, Yasuhiro Tsuji, Masaki Yoshida, Masaya Okamura, Reiko Kuga, Shigeyuki Masaoka, Masaaki Ohba

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

A composite containing a liposome and a lipophilic ruthenium complex was synthesized to regulate an O2 evolution reaction using cerium(iv) ammonium nitrate as an oxidizing reagent. We found that the surrounding environment of the reaction centre is an important factor for controlling the O2 evolution catalytic reaction. We successfully regulated the reaction activity using the linker length of the lipophilic ligand and using the head groups of the phospholipid component.

Original languageEnglish
Pages (from-to)15126-15129
Number of pages4
JournalDalton Transactions
Volume44
Issue number34
DOIs
Publication statusPublished - Apr 29 2015

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Cerium
Ruthenium
Liposomes
Phospholipids
Ligands
Composite materials
ammonium nitrate

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

Cite this

Regulation of a cerium(iv)-driven O2 evolution reaction using composites of liposome and lipophilic ruthenium complexes. / Koshiyama, Tomomi; Kanda, Nao; Iwata, Koki; Honjo, Masayuki; Asada, Sana; Hatae, Tatsuru; Tsuji, Yasuhiro; Yoshida, Masaki; Okamura, Masaya; Kuga, Reiko; Masaoka, Shigeyuki; Ohba, Masaaki.

In: Dalton Transactions, Vol. 44, No. 34, 29.04.2015, p. 15126-15129.

Research output: Contribution to journalArticle

Koshiyama, T, Kanda, N, Iwata, K, Honjo, M, Asada, S, Hatae, T, Tsuji, Y, Yoshida, M, Okamura, M, Kuga, R, Masaoka, S & Ohba, M 2015, 'Regulation of a cerium(iv)-driven O2 evolution reaction using composites of liposome and lipophilic ruthenium complexes', Dalton Transactions, vol. 44, no. 34, pp. 15126-15129. https://doi.org/10.1039/c5dt00793c
Koshiyama, Tomomi ; Kanda, Nao ; Iwata, Koki ; Honjo, Masayuki ; Asada, Sana ; Hatae, Tatsuru ; Tsuji, Yasuhiro ; Yoshida, Masaki ; Okamura, Masaya ; Kuga, Reiko ; Masaoka, Shigeyuki ; Ohba, Masaaki. / Regulation of a cerium(iv)-driven O2 evolution reaction using composites of liposome and lipophilic ruthenium complexes. In: Dalton Transactions. 2015 ; Vol. 44, No. 34. pp. 15126-15129.
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