Regulation of NH-tautomerism in N-confused porphyrin by N-alkylation

Motoki Toganoh, Takaaki Yamamoto, Takayoshi Hihara, Hisanori Akimaru, Hiroyuki Furuta

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

A variety of internally N-alkylated N-confused porphyrins were prepared in a stepwise manner through the protection of the reactive peripheral nitrogen atom. NH-Tautomerism in N-confused porphyrins was found to be regulated by N-alkylation, which enabled us to obtain discrete information on two important NH-tautomers of an N-confused porphyrin.

Original languageEnglish
Pages (from-to)4367-4374
Number of pages8
JournalOrganic and Biomolecular Chemistry
Volume10
Issue number22
DOIs
Publication statusPublished - Jun 14 2012

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Porphyrins
alkylation
Alkylation
porphyrins
tautomers
nitrogen atoms
Nitrogen
Atoms

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Biochemistry

Cite this

Regulation of NH-tautomerism in N-confused porphyrin by N-alkylation. / Toganoh, Motoki; Yamamoto, Takaaki; Hihara, Takayoshi; Akimaru, Hisanori; Furuta, Hiroyuki.

In: Organic and Biomolecular Chemistry, Vol. 10, No. 22, 14.06.2012, p. 4367-4374.

Research output: Contribution to journalArticle

Toganoh, Motoki ; Yamamoto, Takaaki ; Hihara, Takayoshi ; Akimaru, Hisanori ; Furuta, Hiroyuki. / Regulation of NH-tautomerism in N-confused porphyrin by N-alkylation. In: Organic and Biomolecular Chemistry. 2012 ; Vol. 10, No. 22. pp. 4367-4374.
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