Regulation of NH-tautomerism in N-confused porphyrin by N-alkylation

Motoki Toganoh, Takaaki Yamamoto, Takayoshi Hihara, Hisanori Akimaru, Hiroyuki Furuta

    Research output: Contribution to journalArticlepeer-review

    13 Citations (Scopus)

    Abstract

    A variety of internally N-alkylated N-confused porphyrins were prepared in a stepwise manner through the protection of the reactive peripheral nitrogen atom. NH-Tautomerism in N-confused porphyrins was found to be regulated by N-alkylation, which enabled us to obtain discrete information on two important NH-tautomers of an N-confused porphyrin.

    Original languageEnglish
    Pages (from-to)4367-4374
    Number of pages8
    JournalOrganic and Biomolecular Chemistry
    Volume10
    Issue number22
    DOIs
    Publication statusPublished - Jun 14 2012

    All Science Journal Classification (ASJC) codes

    • Biochemistry
    • Physical and Theoretical Chemistry
    • Organic Chemistry

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