Regulation of NH-tautomerism in N-confused porphyrin by N-alkylation

Motoki Toganoh, Takaaki Yamamoto, Takayoshi Hihara, Hisanori Akimaru, Hiroyuki Furuta

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

A variety of internally N-alkylated N-confused porphyrins were prepared in a stepwise manner through the protection of the reactive peripheral nitrogen atom. NH-Tautomerism in N-confused porphyrins was found to be regulated by N-alkylation, which enabled us to obtain discrete information on two important NH-tautomers of an N-confused porphyrin.

Original languageEnglish
Pages (from-to)4367-4374
Number of pages8
JournalOrganic and Biomolecular Chemistry
Volume10
Issue number22
DOIs
Publication statusPublished - Jun 14 2012

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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