Regulation of NH-tautomerism in N-confused porphyrin by N-alkylation

Motoki Toganoh; Takaaki Yamamoto; Takayoshi Hihara; Hisanori Akimaru; Hiroyuki Furuta

doi:10.1039/c2ob25351h

Regulation of NH-tautomerism in N-confused porphyrin by N-alkylation

Motoki Toganoh, Takaaki Yamamoto, Takayoshi Hihara, Hisanori Akimaru, Hiroyuki Furuta

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

A variety of internally N-alkylated N-confused porphyrins were prepared in a stepwise manner through the protection of the reactive peripheral nitrogen atom. NH-Tautomerism in N-confused porphyrins was found to be regulated by N-alkylation, which enabled us to obtain discrete information on two important NH-tautomers of an N-confused porphyrin.

Original language	English
Pages (from-to)	4367-4374
Number of pages	8
Journal	Organic and Biomolecular Chemistry
Volume	10
Issue number	22
DOIs	https://doi.org/10.1039/c2ob25351h
Publication status	Published - Jun 14 2012

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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abstract = "A variety of internally N-alkylated N-confused porphyrins were prepared in a stepwise manner through the protection of the reactive peripheral nitrogen atom. NH-Tautomerism in N-confused porphyrins was found to be regulated by N-alkylation, which enabled us to obtain discrete information on two important NH-tautomers of an N-confused porphyrin.",

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AU - Toganoh, Motoki

AU - Yamamoto, Takaaki

AU - Hihara, Takayoshi

AU - Akimaru, Hisanori

AU - Furuta, Hiroyuki

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Y1 - 2012/6/14

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AB - A variety of internally N-alkylated N-confused porphyrins were prepared in a stepwise manner through the protection of the reactive peripheral nitrogen atom. NH-Tautomerism in N-confused porphyrins was found to be regulated by N-alkylation, which enabled us to obtain discrete information on two important NH-tautomers of an N-confused porphyrin.

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Regulation of NH-tautomerism in N-confused porphyrin by N-alkylation

Abstract

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