Relating microstructure to surface exchange kinetics using in situ optical absorption relaxation

T. Chen, G. F. Harrington, K. Sasaki, N. H. Perry

Research output: Chapter in Book/Report/Conference proceedingConference contribution

5 Citations (Scopus)

Abstract

SrTio65Feo35C3.δ (STF35) thin films grown by pulsed laser deposition were applied as a model system to explore the impact of microstructure on oxygen surface exchange kinetics, of importance for solid oxide cell electrodes. The impact of growth temperature on crystalline quality, orientation, grain size, and surface roughness was evaluated. A contact-free, continuous, in situ Optical Transmission Relaxation (OTR) approach was applied to quantify the films' native surface oxygen exchange coefficients (kchem). In situ crystallization was used to obtain fast surface exchange kinetics via a dynamic nanostructuring process.

Original languageEnglish
Title of host publicationElectrosynthesis of Fuels 4
EditorsH. Xu, G. Brisard, X.-D. Zhou, J. Flake, J. Staser, T. Gur, M. Mogensen, W. Mustain
PublisherElectrochemical Society Inc.
Pages23-31
Number of pages9
Edition43
ISBN (Electronic)9781607685395
DOIs
Publication statusPublished - Jan 1 2016
EventSymposium on Electrosynthesis of Fuels 4 - PRiME 2016/230th ECS Meeting - Honolulu, United States
Duration: Oct 2 2016Oct 7 2016

Publication series

NameECS Transactions
Number43
Volume75
ISSN (Print)1938-6737
ISSN (Electronic)1938-5862

Other

OtherSymposium on Electrosynthesis of Fuels 4 - PRiME 2016/230th ECS Meeting
CountryUnited States
CityHonolulu
Period10/2/1610/7/16

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All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Chen, T., Harrington, G. F., Sasaki, K., & Perry, N. H. (2016). Relating microstructure to surface exchange kinetics using in situ optical absorption relaxation. In H. Xu, G. Brisard, X-D. Zhou, J. Flake, J. Staser, T. Gur, M. Mogensen, ... W. Mustain (Eds.), Electrosynthesis of Fuels 4 (43 ed., pp. 23-31). (ECS Transactions; Vol. 75, No. 43). Electrochemical Society Inc.. https://doi.org/10.1149/07543.0023ecst