Relation between water adsorption in polymer-electrolyte fuel cell and its electric power

Satoshi Fukada, Kazuto Ohba, Atsushi Nomura

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The amount of H2O adsorbed on a Nafion® 117 membrane mounted inside a polymer-electrolyte fuel cell (PEFC) system is determined as a function of temperature and H2O vapor pressure. Its experimental values are related with a product of electric current and terminal voltage when the anode and cathode compartments are supplied with partially moist (0% to 90% in relative humidity) H2 and O2 gases at atmospheric pressure, respectively. Under conditions of H2O vapor pressure lower than 2 × 104 Pa, the amount of H2O adsorbed on the membrane mounted inside the PEFC module is near to its original one that was determined under an unfixed force-free condition, where it is not mounted in cell. However, under conditions of H2O vapor pressure higher than 2 × 104 Pa, the adsorption amount under the mounted state becomes smaller than its original value determined under the unfixed force-free state. At the higher vapor pressure, the electric power generated under the mounted state also becomes lower than its value expected from the adsorption amount under the unfixed state. Thus, it is experimentally clarified that the FC power is deeply related with the amount of H2O adsorbed on the membrane. The H2O adsorption amount depends on whether it is compressed in a FC by an outside mold or not.

Original languageEnglish
Pages (from-to)126-130
Number of pages5
JournalEnergy Conversion and Management
Volume71
DOIs
Publication statusPublished - May 2 2013

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Vapor pressure
Fuel cells
Electrolytes
Adsorption
Polymers
Membranes
Terminals (electric)
Water
Electric currents
Atmospheric pressure
Atmospheric humidity
Anodes
Cathodes
Electric potential
Gases
Temperature

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Nuclear Energy and Engineering
  • Fuel Technology
  • Energy Engineering and Power Technology

Cite this

Relation between water adsorption in polymer-electrolyte fuel cell and its electric power. / Fukada, Satoshi; Ohba, Kazuto; Nomura, Atsushi.

In: Energy Conversion and Management, Vol. 71, 02.05.2013, p. 126-130.

Research output: Contribution to journalArticle

Fukada, Satoshi ; Ohba, Kazuto ; Nomura, Atsushi. / Relation between water adsorption in polymer-electrolyte fuel cell and its electric power. In: Energy Conversion and Management. 2013 ; Vol. 71. pp. 126-130.
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