Remarkably high asymmetric amplification in the chiral lanthanide complex-catalyzed hetero-Diels - Alder reaction: First example of the nonlinear effect in ML3 system

Hiroshi Furuno, Takeshi Hanamoto, Yuichi Sugimoto, Junji Inanaga

Research output: Contribution to journalArticle

71 Citations (Scopus)

Abstract

(formula presented) A remarkably high asymmetric amplification was realized in the Yb[(R)-BNP]3-catalyzed hetero-Diels - Alder reaction as the first example in the metal/chiral ligand 1:3 system. The mechanism may be explained by the autogenetic formation of the enantiopure complex as the most active catalyst. The enantiomer-discriminative formation of homochiral ML3 complexes is quite general within the lanthanide metal ions with similar ionic radii to that of the ytterbium ion.

Original languageEnglish
Pages (from-to)49-52
Number of pages4
JournalOrganic Letters
Volume2
Issue number1
Publication statusPublished - Jan 1 2000

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Ytterbium
Lanthanoid Series Elements
Diels-Alder reactions
Enantiomers
Cycloaddition Reaction
Metal ions
Amplification
Metals
Ions
Ligands
Catalysts
enantiomers
ytterbium
metal ions
catalysts
ligands
radii
metals
ions

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

Remarkably high asymmetric amplification in the chiral lanthanide complex-catalyzed hetero-Diels - Alder reaction : First example of the nonlinear effect in ML3 system. / Furuno, Hiroshi; Hanamoto, Takeshi; Sugimoto, Yuichi; Inanaga, Junji.

In: Organic Letters, Vol. 2, No. 1, 01.01.2000, p. 49-52.

Research output: Contribution to journalArticle

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