Remarkably high catalyst efficiency of a disilaruthenacyclic complex for hydrosilane reduction of carbonyl compounds

Atsushi Tahara, Yusuke Sunada, Takashi Takeshita, Ryoko Inoue, Hideo Nagashima

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

A disilaruthenacyclic complex (1) showed extremely high catalytic activity for hydrosilane reduction of aldehydes and ketones to silyl ethers and secondary and tertiary amides to the corresponding amines. An σ-CAM mechanism was proposed to explain the activity.

Original languageEnglish
Pages (from-to)11192-11195
Number of pages4
JournalChemical Communications
Volume54
Issue number79
DOIs
Publication statusPublished - Jan 1 2018

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Carbonyl compounds
Ethers
Computer aided manufacturing
Ketones
Aldehydes
Amides
Amines
Catalyst activity
Catalysts

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Remarkably high catalyst efficiency of a disilaruthenacyclic complex for hydrosilane reduction of carbonyl compounds. / Tahara, Atsushi; Sunada, Yusuke; Takeshita, Takashi; Inoue, Ryoko; Nagashima, Hideo.

In: Chemical Communications, Vol. 54, No. 79, 01.01.2018, p. 11192-11195.

Research output: Contribution to journalArticle

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