Repeatable photoinduced self-healing of covalently cross-linked polymers through reshuffling of trithiocarbonate units

Yoshifumi Amamoto, Jun Kamada, Hideyuki Otsuka, Atsushi Takahara, Krzysztof Matyjaszewski

Research output: Contribution to journalArticle

302 Citations (Scopus)

Abstract

Well-healed: Polymers cross-linked with trithiocarbonate (TTC) units were prepared by a RAFT polymerization. The repeatable self-healing systems or macroscopic fusions were accomplished by UV irradiation of the cross-linked polymer in solution and in the bulk state. The macroscopic fusion of completely separated parts was successful (see pictures, BA=n-butyl acrylate).

Original languageEnglish
Pages (from-to)1660-1663
Number of pages4
JournalAngewandte Chemie - International Edition
Volume50
Issue number7
DOIs
Publication statusPublished - Feb 11 2011

Fingerprint

Polymers
Fusion reactions
Polymerization
Irradiation
trithiocarbonic acid
n-butyl acrylate

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Catalysis

Cite this

Repeatable photoinduced self-healing of covalently cross-linked polymers through reshuffling of trithiocarbonate units. / Amamoto, Yoshifumi; Kamada, Jun; Otsuka, Hideyuki; Takahara, Atsushi; Matyjaszewski, Krzysztof.

In: Angewandte Chemie - International Edition, Vol. 50, No. 7, 11.02.2011, p. 1660-1663.

Research output: Contribution to journalArticle

@article{8a4203c0e4154cf7950dc733c3c07ce8,
title = "Repeatable photoinduced self-healing of covalently cross-linked polymers through reshuffling of trithiocarbonate units",
abstract = "Well-healed: Polymers cross-linked with trithiocarbonate (TTC) units were prepared by a RAFT polymerization. The repeatable self-healing systems or macroscopic fusions were accomplished by UV irradiation of the cross-linked polymer in solution and in the bulk state. The macroscopic fusion of completely separated parts was successful (see pictures, BA=n-butyl acrylate).",
author = "Yoshifumi Amamoto and Jun Kamada and Hideyuki Otsuka and Atsushi Takahara and Krzysztof Matyjaszewski",
year = "2011",
month = "2",
day = "11",
doi = "10.1002/anie.201003888",
language = "English",
volume = "50",
pages = "1660--1663",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "7",

}

TY - JOUR

T1 - Repeatable photoinduced self-healing of covalently cross-linked polymers through reshuffling of trithiocarbonate units

AU - Amamoto, Yoshifumi

AU - Kamada, Jun

AU - Otsuka, Hideyuki

AU - Takahara, Atsushi

AU - Matyjaszewski, Krzysztof

PY - 2011/2/11

Y1 - 2011/2/11

N2 - Well-healed: Polymers cross-linked with trithiocarbonate (TTC) units were prepared by a RAFT polymerization. The repeatable self-healing systems or macroscopic fusions were accomplished by UV irradiation of the cross-linked polymer in solution and in the bulk state. The macroscopic fusion of completely separated parts was successful (see pictures, BA=n-butyl acrylate).

AB - Well-healed: Polymers cross-linked with trithiocarbonate (TTC) units were prepared by a RAFT polymerization. The repeatable self-healing systems or macroscopic fusions were accomplished by UV irradiation of the cross-linked polymer in solution and in the bulk state. The macroscopic fusion of completely separated parts was successful (see pictures, BA=n-butyl acrylate).

UR - http://www.scopus.com/inward/record.url?scp=79851471046&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=79851471046&partnerID=8YFLogxK

U2 - 10.1002/anie.201003888

DO - 10.1002/anie.201003888

M3 - Article

C2 - 21308927

AN - SCOPUS:79851471046

VL - 50

SP - 1660

EP - 1663

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 7

ER -