Retention Behavior of Calixarenes with Various C60 Bonded Silica Phases in Microcolumn Liquid Chromatography

Kiyokatsu Jinno, Kenji Tanabe, Yoshihiro Saito, Hideo Nagashima, Robert D. Trengove

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Separation of the cyclic molecules, calixarenes, was performed by microcolumn LC using various chemically bonded C60 silica stationary phases. The retention factors of tert-butylcalix[8]arene were higher with the C60 bonded phases than those obtained with an ordinary octadecylsilica (ODS) phase under the same separation conditions. The separation of sulfonated calixarenes was also examined. The retention of these solutes was lower on C60 bonded phases than on ODS. This retention behavior can be explained by the fit of the molecular shape of the solutes to the stationary phase ligand, e.g., lert-butylcalix[8]arene has a bowl-shaped cavity structure.

Original languageEnglish
Pages (from-to)175-177
Number of pages3
JournalAnalytical Communications
Volume34
Issue number6
DOIs
Publication statusPublished - Jan 1 1997
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry

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