Reusable and environmentally friendly ionic trinuclear iron complex catalyst for atom transfer radical polymerization

Shota Niibayashi, Hitoshi Hayakawa, Ren Hua Jin, Hideo Nagashima

Research output: Contribution to journalArticle

66 Citations (Scopus)

Abstract

Ionic iron complex [(Me3tacn)2Fe2Cl 3]+[(Me3tacn)FeCl3]- (1), which is readily soluble in methanol, acted as a powerful catalyst in controlled radical polymerization of styrene and MMA, and showed promising features of removal from the resulting polymers and was reusable after recovery from the crude products.

Original languageEnglish
Pages (from-to)1855-1857
Number of pages3
JournalChemical Communications
Issue number18
DOIs
Publication statusPublished - May 10 2007

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Styrene
Atom transfer radical polymerization
Free radical polymerization
Methanol
Polymers
Iron
Recovery
Catalysts

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Reusable and environmentally friendly ionic trinuclear iron complex catalyst for atom transfer radical polymerization. / Niibayashi, Shota; Hayakawa, Hitoshi; Jin, Ren Hua; Nagashima, Hideo.

In: Chemical Communications, No. 18, 10.05.2007, p. 1855-1857.

Research output: Contribution to journalArticle

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