Reversible electron transfer in a linear {Fe 2Co} trinuclear complex induced by thermal treatment and photoirraditaion

Tao Liu; Da Peng Dong; Shinji Kanegawa; Soonchul Kang; Osamu Sato; Yoshihito Shiota; Kazunari Yoshizawa; Shinya Hayami; Shuo Wu; Cheng He; Chun Ying Duan

doi:10.1002/anie.201201305

Reversible electron transfer in a linear {Fe ₂Co} trinuclear complex induced by thermal treatment and photoirraditaion

Tao Liu, Da Peng Dong, Shinji Kanegawa, Soonchul Kang, Osamu Sato, Yoshihito Shiota, Kazunari Yoshizawa, Shinya Hayami, Shuo Wu, Cheng He, Chun Ying Duan

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article

59 Citations (Scopus)

Abstract

A light change: A linear cyanido-bridged Fe ₂Co compound (see picture) exhibits a reversible, thermally induced cooperative charge transfer transition accompanying spin transition and polar-nonpolar transformation in the trinuclear cluster. The change in magnetic properties and polarity could also be induced by irradiation with light.

Original language	English
Pages (from-to)	4367-4370
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	18
DOIs	https://doi.org/10.1002/anie.201201305
Publication status	Published - Apr 27 2012

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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10.1002/anie.201201305

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Reversible electron transfer in a linear {Fe ₂Co} trinuclear complex induced by thermal treatment and photoirraditaion. / Liu, Tao; Dong, Da Peng; Kanegawa, Shinji; Kang, Soonchul; Sato, Osamu ; Shiota, Yoshihito ; Yoshizawa, Kazunari; Hayami, Shinya; Wu, Shuo; He, Cheng; Duan, Chun Ying.

In: Angewandte Chemie - International Edition, Vol. 51, No. 18, 27.04.2012, p. 4367-4370.

Research output: Contribution to journal › Article

Liu, Tao ; Dong, Da Peng ; Kanegawa, Shinji ; Kang, Soonchul ; Sato, Osamu ; Shiota, Yoshihito ; Yoshizawa, Kazunari ; Hayami, Shinya ; Wu, Shuo ; He, Cheng ; Duan, Chun Ying. / Reversible electron transfer in a linear {Fe ₂Co} trinuclear complex induced by thermal treatment and photoirraditaion. In: Angewandte Chemie - International Edition. 2012 ; Vol. 51, No. 18. pp. 4367-4370.

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