Reversible electron transfer in a linear {Fe 2Co} trinuclear complex induced by thermal treatment and photoirraditaion

Tao Liu, Da Peng Dong, Shinji Kanegawa, Soonchul Kang, Osamu Sato, Yoshihito Shiota, Kazunari Yoshizawa, Shinya Hayami, Shuo Wu, Cheng He, Chun Ying Duan

Research output: Contribution to journalArticle

59 Citations (Scopus)

Abstract

A light change: A linear cyanido-bridged Fe 2Co compound (see picture) exhibits a reversible, thermally induced cooperative charge transfer transition accompanying spin transition and polar-nonpolar transformation in the trinuclear cluster. The change in magnetic properties and polarity could also be induced by irradiation with light.

Original languageEnglish
Pages (from-to)4367-4370
Number of pages4
JournalAngewandte Chemie - International Edition
Volume51
Issue number18
DOIs
Publication statusPublished - Apr 27 2012

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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