Reversible water-induced magnetic and structural conversion of a flexible microporous Ni(II)Fe(III) ferromagnet

Nobuhiro Yanai, Wakako Kaneko, Ko Yoneda, Masaaki Ohba, Susumu Kitagawa

Research output: Contribution to journalArticle

158 Citations (Scopus)

Abstract

A cyanide-bridged bimetallic ferromagnet, [Ni(dipn)]2[Ni(dipn)(H2O)][Fe(CN)6]2·11H2O (dipn = N,N-di(3-aminopropyl)amine) providing a 3-D microporous framework, shows reversible ferromagnet/paramagnet conversion associated with a gaseous water-induced crystal-to-amorphous-like phase transformation.

Original languageEnglish
Pages (from-to)3496-3497
Number of pages2
JournalJournal of the American Chemical Society
Volume129
Issue number12
DOIs
Publication statusPublished - Mar 28 2007
Externally publishedYes

Fingerprint

Magnets
Cyanides
Amines
Phase transitions
Crystals
Water
N,N-di(3-aminopropyl)amine

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Reversible water-induced magnetic and structural conversion of a flexible microporous Ni(II)Fe(III) ferromagnet. / Yanai, Nobuhiro; Kaneko, Wakako; Yoneda, Ko; Ohba, Masaaki; Kitagawa, Susumu.

In: Journal of the American Chemical Society, Vol. 129, No. 12, 28.03.2007, p. 3496-3497.

Research output: Contribution to journalArticle

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