Reversible water-induced magnetic and structural conversion of a flexible microporous Ni(II)Fe(III) ferromagnet

Nobuhiro Yanai; Wakako Kaneko; Ko Yoneda; Masaaki Ohba; Susumu Kitagawa

doi:10.1021/ja069166b

Reversible water-induced magnetic and structural conversion of a flexible microporous Ni(II)Fe(III) ferromagnet

Nobuhiro Yanai, Wakako Kaneko, Ko Yoneda, Masaaki Ohba, Susumu Kitagawa

Research output: Contribution to journal › Article › peer-review

175 Citations (Scopus)

Abstract

A cyanide-bridged bimetallic ferromagnet, [Ni(dipn)]₂[Ni(dipn)(H₂O)][Fe(CN)₆]₂·11H₂O (dipn = N,N-di(3-aminopropyl)amine) providing a 3-D microporous framework, shows reversible ferromagnet/paramagnet conversion associated with a gaseous water-induced crystal-to-amorphous-like phase transformation.

Original language	English
Pages (from-to)	3496-3497
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	129
Issue number	12
DOIs	https://doi.org/10.1021/ja069166b
Publication status	Published - Mar 28 2007
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja069166b

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abstract = "A cyanide-bridged bimetallic ferromagnet, [Ni(dipn)]2[Ni(dipn)(H2O)][Fe(CN)6]2·11H2O (dipn = N,N-di(3-aminopropyl)amine) providing a 3-D microporous framework, shows reversible ferromagnet/paramagnet conversion associated with a gaseous water-induced crystal-to-amorphous-like phase transformation.",

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AU - Yanai, Nobuhiro

AU - Kaneko, Wakako

AU - Yoneda, Ko

AU - Ohba, Masaaki

AU - Kitagawa, Susumu

PY - 2007/3/28

Y1 - 2007/3/28

N2 - A cyanide-bridged bimetallic ferromagnet, [Ni(dipn)]2[Ni(dipn)(H2O)][Fe(CN)6]2·11H2O (dipn = N,N-di(3-aminopropyl)amine) providing a 3-D microporous framework, shows reversible ferromagnet/paramagnet conversion associated with a gaseous water-induced crystal-to-amorphous-like phase transformation.

AB - A cyanide-bridged bimetallic ferromagnet, [Ni(dipn)]2[Ni(dipn)(H2O)][Fe(CN)6]2·11H2O (dipn = N,N-di(3-aminopropyl)amine) providing a 3-D microporous framework, shows reversible ferromagnet/paramagnet conversion associated with a gaseous water-induced crystal-to-amorphous-like phase transformation.

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Reversible water-induced magnetic and structural conversion of a flexible microporous Ni(II)Fe(III) ferromagnet

Abstract

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