Rhenium-catalyzed addition of -enamino esters to allenes

Yoichiro Kuninobu, Atsuhiro Yamashita, Shun Ichi Yamamoto, Salprima Yudha S., Kazuhiko Takai

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Treatment of β-enamino esters with terminal allenes in the presence of a catalytic amount of a rhenium complex, [ReBr(CO)3(thf)] 2, gave α-alkenylated β-imino or β-enamino esters. In this reaction, a new carbon-carbon bond is formed between the active methylene moiety of the β-enamino esters and the -carbon of the terminal allenes.

Original languageEnglish
Pages (from-to)3027-3031
Number of pages5
JournalSynlett
Issue number18
DOIs
Publication statusPublished - Dec 21 2009
Externally publishedYes

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Rhenium
Esters
Carbon
Carbon Monoxide
propadiene

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

Cite this

Kuninobu, Y., Yamashita, A., Yamamoto, S. I., Yudha S., S., & Takai, K. (2009). Rhenium-catalyzed addition of -enamino esters to allenes. Synlett, (18), 3027-3031. https://doi.org/10.1055/s-0029-1218281

Rhenium-catalyzed addition of -enamino esters to allenes. / Kuninobu, Yoichiro; Yamashita, Atsuhiro; Yamamoto, Shun Ichi; Yudha S., Salprima; Takai, Kazuhiko.

In: Synlett, No. 18, 21.12.2009, p. 3027-3031.

Research output: Contribution to journalArticle

Kuninobu, Y, Yamashita, A, Yamamoto, SI, Yudha S., S & Takai, K 2009, 'Rhenium-catalyzed addition of -enamino esters to allenes', Synlett, no. 18, pp. 3027-3031. https://doi.org/10.1055/s-0029-1218281
Kuninobu Y, Yamashita A, Yamamoto SI, Yudha S. S, Takai K. Rhenium-catalyzed addition of -enamino esters to allenes. Synlett. 2009 Dec 21;(18):3027-3031. https://doi.org/10.1055/s-0029-1218281
Kuninobu, Yoichiro ; Yamashita, Atsuhiro ; Yamamoto, Shun Ichi ; Yudha S., Salprima ; Takai, Kazuhiko. / Rhenium-catalyzed addition of -enamino esters to allenes. In: Synlett. 2009 ; No. 18. pp. 3027-3031.
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