Rhenium-catalyzed diastereoselective synthesis of aminoindanes via the insertion of allenes into a C-H bond

Yoichiro Kuninobu, Peng Yu, Kazuhiko Takai

Research output: Contribution to journalArticle

70 Citations (Scopus)

Abstract

Figure Presented. Aminoindane derivatives were synthesized diastereoselectively by the treatment of aromatic imines with allenes in the presence of a catalytic amount of a rhenium complex, [HRe(CO)4] n. The allenes inserted into the aromatic C-H bonds.

Original languageEnglish
Pages (from-to)4274-4276
Number of pages3
JournalOrganic Letters
Volume12
Issue number19
DOIs
Publication statusPublished - Oct 1 2010
Externally publishedYes

Fingerprint

Rhenium
rhenium
imines
insertion
Imines
Carbon Monoxide
synthesis
Derivatives
propadiene

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

Rhenium-catalyzed diastereoselective synthesis of aminoindanes via the insertion of allenes into a C-H bond. / Kuninobu, Yoichiro; Yu, Peng; Takai, Kazuhiko.

In: Organic Letters, Vol. 12, No. 19, 01.10.2010, p. 4274-4276.

Research output: Contribution to journalArticle

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abstract = "Figure Presented. Aminoindane derivatives were synthesized diastereoselectively by the treatment of aromatic imines with allenes in the presence of a catalytic amount of a rhenium complex, [HRe(CO)4] n. The allenes inserted into the aromatic C-H bonds.",
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