Rhenium complexes of N-methyl N-confused tetraphenylporphyrin and its normal isomer

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Abstract

The rhenium tricarbonyl complexes bearing tridentate porphyrin ligands, N-methyltatraphenylporphyrin and N-methyl N-confused tatraphenylporphyrin, were prepared and their structures were studied by X-ray crystallographic analysis. Drastic change of HOMO-LUMO gap by confusion of N-methylpyrrole moiety was illustrated from experimental and theoretical studies.

Original languageEnglish
Pages (from-to)1034-1035
Number of pages2
JournalChemistry Letters
Volume34
Issue number7
DOIs
Publication statusPublished - Jul 5 2005

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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