Rhenium complexes of peripherally π-extended N-confused porphyrins

Takaaki Yamamoto; Motoki Toganoh; Shigeki Mori; Hidemitsu Uno; Hiroyuki Furuta

doi:10.1039/c2sc20708g

Rhenium complexes of peripherally π-extended N-confused porphyrins

Takaaki Yamamoto, Motoki Toganoh, Shigeki Mori, Hidemitsu Uno, Hiroyuki Furuta

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18 Citations (Scopus)

Abstract

Peripherally π-extended N-confused porphyrin rhenium complexes were synthesized by the rhenium-mediated reactions of N-confused porphyrins with 2-methyl azaarene and the structures were elucidated by X-ray crystallographic analyses. Extension of the π-conjugation in the complexes was supported by the absorption spectra, electrochemical measurements and theoretical calculations.

Original language	English
Pages (from-to)	3241-3248
Number of pages	8
Journal	Chemical Science
Volume	3
Issue number	11
DOIs	https://doi.org/10.1039/c2sc20708g
Publication status	Published - Nov 2012

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1039/c2sc20708g

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abstract = "Peripherally π-extended N-confused porphyrin rhenium complexes were synthesized by the rhenium-mediated reactions of N-confused porphyrins with 2-methyl azaarene and the structures were elucidated by X-ray crystallographic analyses. Extension of the π-conjugation in the complexes was supported by the absorption spectra, electrochemical measurements and theoretical calculations.",

author = "Takaaki Yamamoto and Motoki Toganoh and Shigeki Mori and Hidemitsu Uno and Hiroyuki Furuta",

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AU - Uno, Hidemitsu

AU - Furuta, Hiroyuki

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N2 - Peripherally π-extended N-confused porphyrin rhenium complexes were synthesized by the rhenium-mediated reactions of N-confused porphyrins with 2-methyl azaarene and the structures were elucidated by X-ray crystallographic analyses. Extension of the π-conjugation in the complexes was supported by the absorption spectra, electrochemical measurements and theoretical calculations.

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Rhenium complexes of peripherally π-extended N-confused porphyrins

Abstract

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