Rheo-SANS study of an aqueous suspension of poly (methyl methacrylate-co-styrene) particle

Hiroshi Watanabe, Yumi Matsumiya, Toshiji Kanaya, Yoshiaki Takahashi, Misao Horigome, Makoto Yada, Atsushi Miyakawa

Research output: Contribution to journalArticlepeer-review

Abstract

For an aqueous suspension of poly (methyl methacrylate-co-styrene) (MS) particles, viscosity η and small-angle neutron scattering (SANS) intensity I(q) were measured under steady shear. The MS particles had partially screened surface charges. In the quiescent state, the particle distribution detected through the I(q) profile was isotropic and essentially liquid-like but also exhibited a weak, local order. Under steady shear, this distribution was distorted just moderately, and the η strongly decreased with increasing shear rate γ̇. Thus, this thinning of η was related to the weak distortion of the particle distribution. Furthermore, the thermodynamic stress σT estimated from the I(q) profile under the shear increased only weakly with increasing γ̇, and the corresponding viscosity ηT (=σT/γ̇) was close to the η data. These results strongly suggested that the thinning of the MS suspension reflected the nonlinearity of σT.

Original languageEnglish
Pages (from-to)269-275
Number of pages7
JournalNihon Reoroji Gakkaishi
Volume30
Issue number5
DOIs
Publication statusPublished - Dec 1 2002

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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