Rhodium-catalysed synthesis of multi-substituted silylindenes from aryl alkynes and hydrosilanes via C-H bond activation

Shunsuke Sueki; Yoichiro Kuninobu

doi:10.1039/c5cc01569c

Rhodium-catalysed synthesis of multi-substituted silylindenes from aryl alkynes and hydrosilanes via C-H bond activation

Shunsuke Sueki, Yoichiro Kuninobu

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

We successfully developed rhodium-catalysed synthesis of multi-substituted silylindenes from 2 equivalents of aryl alkynes and 1 equivalent of hydrosilanes in moderate to good yields via C-H bond activation for the first time. The silyl groups of the obtained silylindenes could be converted to several other functional groups.

Original language	English
Pages (from-to)	7685-7688
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	36
DOIs	https://doi.org/10.1039/c5cc01569c
Publication status	Published - May 4 2015
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "We successfully developed rhodium-catalysed synthesis of multi-substituted silylindenes from 2 equivalents of aryl alkynes and 1 equivalent of hydrosilanes in moderate to good yields via C-H bond activation for the first time. The silyl groups of the obtained silylindenes could be converted to several other functional groups.",

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Y1 - 2015/5/4

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AB - We successfully developed rhodium-catalysed synthesis of multi-substituted silylindenes from 2 equivalents of aryl alkynes and 1 equivalent of hydrosilanes in moderate to good yields via C-H bond activation for the first time. The silyl groups of the obtained silylindenes could be converted to several other functional groups.

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Rhodium-catalysed synthesis of multi-substituted silylindenes from aryl alkynes and hydrosilanes via C-H bond activation

Abstract

All Science Journal Classification (ASJC) codes

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