Rhodium-catalyzed phosphorylation reaction of water-soluble disulfides using hypodiphosphoric acid tetraalkyl esters in water

Mieko Arisawa; Kohei Fukumoto; Masahiko Yamaguchi

doi:10.1039/d0ra02377a

Rhodium-catalyzed phosphorylation reaction of water-soluble disulfides using hypodiphosphoric acid tetraalkyl esters in water

Mieko Arisawa, Kohei Fukumoto, Masahiko Yamaguchi

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

RhCl₃ catalyzed the exchange reaction of disulfides and hypodiphosphoric acid tetraalkyl esters in water under homogeneous conditions, which indicated the hypodiphosphoric acid tetraalkyl esters to be novel and efficient phosphorylation reagents in water. The reaction was used in the phosphorylation of unprotected glutathione disulfide.

Original language	English
Pages (from-to)	13820-13823
Number of pages	4
Journal	RSC Advances
Volume	10
Issue number	23
DOIs	https://doi.org/10.1039/d0ra02377a
Publication status	Published - Apr 6 2020
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Chemical Engineering(all)

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10.1039/d0ra02377a

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title = "Rhodium-catalyzed phosphorylation reaction of water-soluble disulfides using hypodiphosphoric acid tetraalkyl esters in water",

abstract = "RhCl3 catalyzed the exchange reaction of disulfides and hypodiphosphoric acid tetraalkyl esters in water under homogeneous conditions, which indicated the hypodiphosphoric acid tetraalkyl esters to be novel and efficient phosphorylation reagents in water. The reaction was used in the phosphorylation of unprotected glutathione disulfide.",

author = "Mieko Arisawa and Kohei Fukumoto and Masahiko Yamaguchi",

note = "Funding Information: This research was supported by the Platform Project for Supporting Drug Discovery and Life Science Research from AMED under Grant number JP18am0101100, JSPS KAKENHI Grant number 17K19112, and Tohoku University Center for Gender Equality Promotion (TUMUG). Publisher Copyright: {\textcopyright} 2020 The Royal Society of Chemistry.",

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doi = "10.1039/d0ra02377a",

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AU - Arisawa, Mieko

AU - Fukumoto, Kohei

AU - Yamaguchi, Masahiko

N1 - Funding Information: This research was supported by the Platform Project for Supporting Drug Discovery and Life Science Research from AMED under Grant number JP18am0101100, JSPS KAKENHI Grant number 17K19112, and Tohoku University Center for Gender Equality Promotion (TUMUG). Publisher Copyright: © 2020 The Royal Society of Chemistry.

PY - 2020/4/6

Y1 - 2020/4/6

N2 - RhCl3 catalyzed the exchange reaction of disulfides and hypodiphosphoric acid tetraalkyl esters in water under homogeneous conditions, which indicated the hypodiphosphoric acid tetraalkyl esters to be novel and efficient phosphorylation reagents in water. The reaction was used in the phosphorylation of unprotected glutathione disulfide.

AB - RhCl3 catalyzed the exchange reaction of disulfides and hypodiphosphoric acid tetraalkyl esters in water under homogeneous conditions, which indicated the hypodiphosphoric acid tetraalkyl esters to be novel and efficient phosphorylation reagents in water. The reaction was used in the phosphorylation of unprotected glutathione disulfide.

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U2 - 10.1039/d0ra02377a

DO - 10.1039/d0ra02377a

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JF - RSC Advances

IS - 23

ER -

Rhodium-catalyzed phosphorylation reaction of water-soluble disulfides using hypodiphosphoric acid tetraalkyl esters in water

Abstract

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