Rhodium-catalyzed synthesis of 1-alkynylphosphine oxides from 1-alkynes and tetraphenylbiphosphine

Mieko Arisawa, Masato Onoda, Chieko Hori, Masahiko Yamaguchi

Research output: Contribution to journalArticlepeer-review

25 Citations (Scopus)

Abstract

A rhodium complex RhH(PPh3)4 catalyzes the C-P bond forming reaction of 1-alkynes and tetraphenylbiphosphine in the presence of 2,4-dimethylnitrobenzene giving 1-alkynylphosphines and its oxides.

Original languageEnglish
Pages (from-to)5211-5213
Number of pages3
JournalTetrahedron Letters
Volume47
Issue number29
DOIs
Publication statusPublished - Jul 17 2006
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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