Rhodium-catalyzed thiophosphinylation and phosphinylation reactions of disulfides and diselenides

Mieko Arisawa; Tetsuya Ono; Masahiko Yamaguchi

doi:10.1016/j.tetlet.2005.06.109

Rhodium-catalyzed thiophosphinylation and phosphinylation reactions of disulfides and diselenides

Mieko Arisawa, Tetsuya Ono, Masahiko Yamaguchi

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

Alkyl and aryl dithiophosphinates were synthesized by the reaction of disulfides with biphosphine disulfides in the presence of RhH(PPh ₃)₄ and 1,2-diphenylphosphinoethane (dppe). The catalyst also promoted synthesis of thiophosphinates and selenothiophosphinates from disulfides and diselenides.

Original language	English
Pages (from-to)	5669-5671
Number of pages	3
Journal	Tetrahedron Letters
Volume	46
Issue number	34
DOIs	https://doi.org/10.1016/j.tetlet.2005.06.109
Publication status	Published - Aug 22 2005
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2005.06.109

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title = "Rhodium-catalyzed thiophosphinylation and phosphinylation reactions of disulfides and diselenides",

abstract = "Alkyl and aryl dithiophosphinates were synthesized by the reaction of disulfides with biphosphine disulfides in the presence of RhH(PPh 3)4 and 1,2-diphenylphosphinoethane (dppe). The catalyst also promoted synthesis of thiophosphinates and selenothiophosphinates from disulfides and diselenides.",

author = "Mieko Arisawa and Tetsuya Ono and Masahiko Yamaguchi",

note = "Funding Information: This work was supported by JSPS (Nos. 16109001 and 17689001). M.A. expresses her thanks for financial support from the New Energy and Industrial Technology Development Organization (NEDO) of Japan (No. 02A44003d) and the Takeda Science Foundation. ",

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doi = "10.1016/j.tetlet.2005.06.109",

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journal = "Tetrahedron Letters",

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T1 - Rhodium-catalyzed thiophosphinylation and phosphinylation reactions of disulfides and diselenides

AU - Arisawa, Mieko

AU - Ono, Tetsuya

AU - Yamaguchi, Masahiko

N1 - Funding Information: This work was supported by JSPS (Nos. 16109001 and 17689001). M.A. expresses her thanks for financial support from the New Energy and Industrial Technology Development Organization (NEDO) of Japan (No. 02A44003d) and the Takeda Science Foundation.

PY - 2005/8/22

Y1 - 2005/8/22

N2 - Alkyl and aryl dithiophosphinates were synthesized by the reaction of disulfides with biphosphine disulfides in the presence of RhH(PPh 3)4 and 1,2-diphenylphosphinoethane (dppe). The catalyst also promoted synthesis of thiophosphinates and selenothiophosphinates from disulfides and diselenides.

AB - Alkyl and aryl dithiophosphinates were synthesized by the reaction of disulfides with biphosphine disulfides in the presence of RhH(PPh 3)4 and 1,2-diphenylphosphinoethane (dppe). The catalyst also promoted synthesis of thiophosphinates and selenothiophosphinates from disulfides and diselenides.

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U2 - 10.1016/j.tetlet.2005.06.109

DO - 10.1016/j.tetlet.2005.06.109

M3 - Article

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VL - 46

SP - 5669

EP - 5671

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 34

ER -

Rhodium-catalyzed thiophosphinylation and phosphinylation reactions of disulfides and diselenides

Abstract

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