Rhodium catalyzed transformation of propargylamines to 2-silylmethyl-2-alkenals: Formal silylformylation of allenes

Isamu Matsuda, Jun Sakakibara, Hirofumi Inoue, Hideo Nagashima

Research output: Contribution to journalArticle

43 Citations (Scopus)

Abstract

Propargylamines are effectively transformed to 2-dimethylphenylsilylmethyl-2-alkenals by the interaction of two equivalents of Me2PhSiH under silylformylation conditions catalyzed by Rh4(CO)12. The products are not obtained directly by silylformylation of the corresponding allenes.

Original languageEnglish
Pages (from-to)5799-5802
Number of pages4
JournalTetrahedron Letters
Volume33
Issue number39
DOIs
Publication statusPublished - Sep 22 1992
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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