Rhodium nanoparticles supported on carbon nanofibers as an arene hydrogénation catalyst highly tolerant to a coexisting epoxido group

Yukihiro Motoyama; Mikihiro Takasaki; Seong Ho Yoon; Isao Mochida; Hideo Nagashima

doi:10.1021/ol902018g

Rhodium nanoparticles supported on carbon nanofibers as an arene hydrogénation catalyst highly tolerant to a coexisting epoxido group

Yukihiro Motoyama, Mikihiro Takasaki, Seong Ho Yoon, Isao Mochida, Hideo Nagashima

Research output: Contribution to journal › Article › peer-review

59 Citations (Scopus)

Abstract

Rhodium nanoparticles supported on a carbon nanofiber (Rh/CNF-T) show high catalytic activity toward arene hydrogenation under mild conditions in high turnover numbers without leaching the Rh species; the reaction is highly tolerant to epoxido groups, which often undergo ring-opening hydrogenation with conventional catalysts.

Original language	English
Pages (from-to)	5042-5045
Number of pages	4
Journal	Organic letters
Volume	11
Issue number	21
DOIs	https://doi.org/10.1021/ol902018g
Publication status	Published - Nov 5 2009

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol902018g

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title = "Rhodium nanoparticles supported on carbon nanofibers as an arene hydrog{\'e}nation catalyst highly tolerant to a coexisting epoxido group",

abstract = "Rhodium nanoparticles supported on a carbon nanofiber (Rh/CNF-T) show high catalytic activity toward arene hydrogenation under mild conditions in high turnover numbers without leaching the Rh species; the reaction is highly tolerant to epoxido groups, which often undergo ring-opening hydrogenation with conventional catalysts.",

author = "Yukihiro Motoyama and Mikihiro Takasaki and Yoon, {Seong Ho} and Isao Mochida and Hideo Nagashima",

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AU - Motoyama, Yukihiro

AU - Takasaki, Mikihiro

AU - Yoon, Seong Ho

AU - Mochida, Isao

AU - Nagashima, Hideo

PY - 2009/11/5

Y1 - 2009/11/5

N2 - Rhodium nanoparticles supported on a carbon nanofiber (Rh/CNF-T) show high catalytic activity toward arene hydrogenation under mild conditions in high turnover numbers without leaching the Rh species; the reaction is highly tolerant to epoxido groups, which often undergo ring-opening hydrogenation with conventional catalysts.

AB - Rhodium nanoparticles supported on a carbon nanofiber (Rh/CNF-T) show high catalytic activity toward arene hydrogenation under mild conditions in high turnover numbers without leaching the Rh species; the reaction is highly tolerant to epoxido groups, which often undergo ring-opening hydrogenation with conventional catalysts.

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Rhodium nanoparticles supported on carbon nanofibers as an arene hydrogénation catalyst highly tolerant to a coexisting epoxido group

Abstract

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